位置:成果数据库 > 期刊 > 期刊详情页
低品位软锰矿降解糖蜜酒精废液中焦糖色素的脱色动力学
  • 期刊名称:过程工程学报,2009,9(3):480-485
  • 时间:0
  • 分类:TF803.21[冶金工程—有色金属冶金] TQ028.96[化学工程]
  • 作者机构:[1]广西大学化学化工学院,广西南宁530004
  • 相关基金:基金项目:国家自然科学基金资助项目(编号:20866001);广西自然科学基金资助项目(编号:桂科自0832035)
  • 相关项目:糖蜜酒精废液中多组分有机物耦合浸出软锰矿的机理研究
中文摘要:

用合成的双倍焦糖色素模拟糖蜜酒精废液中的焦糖色素,研究了硫酸介质中低品位软锰矿氧化降解焦糖色素的脱色动力学,考察了焦糖色素初始浓度、硫酸浓度、软锰矿用量和反应温度对焦糖色素降解脱色速率的影响.结果表明,焦糖色素的降解脱色速率随焦糖色素初始浓度、硫酸浓度、软锰矿用量和反应温度的增加而增加.对实验数据进行拟合,得到了焦糖色素降解脱色动力学模型,其脱色过程的表观活化能为24.4kJ/mol,焦糖色素、硫酸和软锰矿的表观反应级数分别为2.0,0.58和1.09.

英文摘要:

The caramel in molasses alcohol wastewater was simulated with synthesized diploid caramel, and the decolorizing kinetics of its oxidation degraded by low-grade pyrolusite studied. The effects of reaction temperature, pyrolusite dosage, initial concentration of caramel and sulphuric acid on the decolorizing rate of caramel were investigated. The results showed that the decolorizing rate increased with the increase of reaction temperature, pyrolusite dosage, initial concentration of caramel and sulphuric acid. The experimental data for the decolorizing rate of caramel were analyzed, and the kinetic model established. The apparent activation energy was calculated to be 24.4 kJ/mol, and the reaction order of caramel, sulphuric acid and pyrolusite were 2.0, 0.58 and 1.09, respectively.

同期刊论文项目
同项目期刊论文