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麦草亚铵法黑液超滤前后的物化性能
  • ISSN号:1000-2006
  • 期刊名称:《南京林业大学学报:自然科学版》
  • 时间:0
  • 分类:TQ949[化学工程] X793[环境科学与工程—环境工程]
  • 作者机构:[1]南京林业大学,江苏省制浆造纸科学与技术重点实验室,江苏南京210037
  • 相关基金:国家自然科学基金资助项目(50373020)
中文摘要:

采用超滤法对麦草亚铵法制浆黑液进行处理,并对处理前后的黑液进行物化性能的对比研究;采用凝胶色谱法对黑液和截留液中的木质素分子质量及其分布进行分析。结果表明:超滤纯化了黑液,使其中的木质素含量提高17.42%,灰分减少18.22%;透过液的木质素分子质量主要集中在小于4950的部分(占82.86%);截留液的木质素分子质量小于4950部分的比例下降了17.33%,高分子质量部分比例增加;截留液中的主要官能团——磺酸基、羧基和酚羟基的含量均比黑液中的高;截留液的表面张力较原液下降了2.2mN/m;净浆流动度提高了45.7%。通过超滤可有限增强黑液的应用性能。

英文摘要:

Uhrafihration treatment of the ammonia sulfite pulping black liquor of wheat straw and its effects on chemical structure characteristics and physical properties were studied. The results showed that after uhrafihration the content of lignin in retentate increased by 17. 42% and the content of ash decreased by 18.22%. It was seen that the molecular weight distribution of lignin in black liquor and retentate were determined by Gel Chromatography. The molecular weight of lignin in permeate mainly concentrated in the range less than 4 950 with the occupation of 82.86% , and the molecular weight of lignin in retentate was higher than that in black liquor. The contents of sulfonic, carboxyl, phenolic hydroxyl groups which are the main functional groups in retentate were all more than those in black liquor. Meanwhile, after uhrafihration, the retentate had better performance than black liquor as surfactant, as additive in concrete and as dispersant. Compared with black liquor, its surface tension at 1% was 54. 7 raN/m, and dropped 2.2 mN/m. Clean solution' s fluidity improved from 70mm to 102mm. However, the performance of retentate was limited by uhrafihration so that it would be further improved by modification.

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期刊信息
  • 《南京林业大学学报:自然科学版》
  • 中国科技核心期刊
  • 主管单位:江苏省教育厅
  • 主办单位:南京林业大学
  • 主编:曹福亮
  • 地址:南京市龙蟠路159号南京林业大学学报编辑部
  • 邮编:210037
  • 邮箱:xuebao@njfu.edu.cn
  • 电话:025-85428247 85427076
  • 国际标准刊号:ISSN:1000-2006
  • 国内统一刊号:ISSN:32-1161/S
  • 邮发代号:28-16
  • 获奖情况:
  • 全国高校优秀学术期刊一等奖、江苏省自然科学学报...
  • 国内外数据库收录:
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  • 被引量:21690