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白光有机电致发光器件中Rubrene超薄层的发光性能
  • ISSN号:0251-0790
  • 期刊名称:《高等学校化学学报》
  • 时间:0
  • 分类:O644.11[理学—物理化学;理学—化学]
  • 作者机构:[1]电子科技大学光电信息学院,电子薄膜与集成器件国家重点实验室,成都610054
  • 相关基金:国家自然科学基金(批准号:60736005)、国家自然科学基金创新群体基金(批准号:60721001)、国家杰出青年基金(批准号:60425101)、教育部新世纪优秀人才计划(批准号:NCET-06-0812)和电子科技大学中青年学术带头人计划(批准号:060206)资助.
中文摘要:

以黄光荧光染料5,6,11,12-Tetraphenylnaphthacene(Rubrene)作为超薄层,制备了白光有机电致发光器件,并采用改变荧光超薄层厚度的方法,通过表征器件的电致发光光谱,分析了超薄层中染料浓度对器件性能的影响.研究结果表明,在荧光染料Rubrene的厚度为0.3am时,器件可以同时实现黄光和蓝光的等强度发射,从而得到性能优良的白光器件,最高亮度达到3700cd/m^2,颜色坐标为(0.32,0.33).器件中蓝光来自N,N'-Bis-(1-naphthyl)-N,N’-biphenyl-1,1’biphenyl-4,4'-diamine(NPB)的电致发光,而器件优良的光电性能是由于Rubrene分子直接载流子陷阱(DCT)效应和NPB分子向Rubrene分子传递能量的协同作用所致.

英文摘要:

The development of white organic light-emitting devices (WOLEDs) generated lots of interests in this area, as these devices can be employed not only as illumination fight source but also as backlight source candidate for next generation flat-panel displays. To achieve white emission from OLEDs, an additive mixture of three primary colors, i.e. , red, green, and blue (RGB) or a complementary color modification is indispensable. Comparing to the undoped device, the performances of doped red OLEDs and blue OLEDs were enhanced. Thereafter doping highly fluorescent dyes in emission layer became an important approach to realize WOLEDs with excellent performance. WOLEDs based on an uhrathin layer of yellow fluorescent dye 5,6,11, 12-tetraphenylnaphthacene(Rubrene) were investigated. By changing the thickness of ultrathin dye layer fabricated by thermal vacuum deposition and analyzing electroluminescent(EL) spectra of devices, concentration effect of dye on the performance of the devices was analyzed. The results showed that the balanced intensity of yellow and blue light for white light emission was obtained in the device when the thickness of fluorescent dye Rubrene was 0.3 nm. The blue light emitted from fluorescent material N, N'-bis-( 1-naphthyl ) -N, N'-biphenyl-1,1 '-biphenyl-4,4'-diamine(NPB) and the yellow light was from fluorescent Rubrene dye. A maximum luminance of 3700 cd/m2 was obtained. The Commissions International L'Eclairage(CIE) coordinates located at(0.32, 0.33), which is almost consistent with the optimum white CIE of (0. 333, 0. 333). The high performance of WOLED was ascribed to direct carrier trapping(DCT) effect of Rubrene and efficient energy transfer from NPB to Rubrene.

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期刊信息
  • 《高等学校化学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中华人民共和国教育部
  • 主办单位:吉林大学 南开大学
  • 主编:周其凤
  • 地址:吉林大学南胡校区
  • 邮编:130012
  • 邮箱:cjcu@jlu.edu.cn
  • 电话:0431-88499216
  • 国际标准刊号:ISSN:0251-0790
  • 国内统一刊号:ISSN:22-1131/O6
  • 邮发代号:12-40
  • 获奖情况:
  • 首届及第二届国家期刊奖,连续两届“百种中国杰出学术期刊”,中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:50676