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孔洞和孪晶界对银纳米线形变行为联合影响的分子动力学模拟
  • ISSN号:1000-6818
  • 期刊名称:《物理化学学报》
  • 时间:0
  • 分类:TQ174.758[化学工程—陶瓷工业;化学工程—硅酸盐工业] TB383[一般工业技术—材料科学与工程]
  • 作者机构:[1]State Key Laboratory of Chemo/Biosensing and Chemometrics. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China, [2]Huaihua Key Laboratory of Functional Inorganic & Polymeric Materials, Huaihua University, Huaihua 418000, China, [3]Department of Materials and Chemical Engineering, Hunan Institute of Technology, Hengyang 421008, China
  • 相关基金:jointly funded by the National Natural Science Foundation of China(Nos.21476066 and 51271074);the Key Project of Hunan provincial Education Department of China(No.15A146)
中文摘要:

核心壳组织了钴涂的钨碳化物(WC/Co ) 合成粉末被断断续续的电极淀积准备。象 WC/Co 的形成上的当前的密度,单个免职脉搏, pH 值和表面活化剂那样的进程参数的影响被扫描电子显微镜学(SEM ) 调查并且描绘,电气化学的车站, acidometer 和 X 光检查衍射(XRD ) 技术。有 54% 钴内容的合成粉末在 40 牵獥映潲 ? 的操作温度与 10g dm 3 WC 粉末的负担和 600r min 1 的激动人心的速度在 16A dm 2, 的当前的密度被制作 ??? 琠?????. 吗?

英文摘要:

Core-shell structured cobalt coated tungsten carbide(WC/Co) composite powders were prepared by intermittent electrodeposition. The influence of process parameters such as current density, single deposition pulse, p H value and surfactants on the formation of WC/Co was investigated and characterized by scanning electron microscopy(SEM), electrochemical station, acidometer and X-ray diffraction(XRD) techniques.The composite powders with 54% cobalt content were fabricated at a current density of 16 A dm-2, with a load of 10 g dm-3WC powders and a stirring speed of 600 r min-1at an operation temperature of 40 ± 2 °C,and 90% current efficiency was obtained with a single deposition pulse of 1.5 min and single stirring pulse of 2 min during 12 min efficient electrodeposition time. The uniformly distributed WC/Co powders could be obtained in the cobalt electrolyte containing 300 mg dm-3PEG-2000. The spherical cobalt grains coated WC particles were prepared in the p H 4-5 electrolyte at the Co deposition rate of 0.58 g min-1. A practical process for high efficient production of WC/Co powders by electrodeposition was developed in the present work.

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期刊信息
  • 《物理化学学报》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:北京大学化学与分子工程学院承办
  • 主编:刘忠范
  • 地址:北京大学化学楼
  • 邮编:100871
  • 邮箱:whxb@pku.edu.cn
  • 电话:010-62751724
  • 国际标准刊号:ISSN:1000-6818
  • 国内统一刊号:ISSN:11-1892/O6
  • 邮发代号:82-163
  • 获奖情况:
  • 中文核心期刊
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),英国科学文摘数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:24781