中文摘要：

从热力学上对石煤空白焙烧过程中发生的相关氧化反应进行了分析.有机碳、黄铁矿及钒的氧化反应,在热力学上都可自发进行,有机质和黄铁矿比钒更容易氧化.有机碳和黄铁矿的存在,对钒的氧化有阻碍作用,若预先脱碳或脱除黄铁矿,则有利于钒的氧化.

英文摘要：

Relevant oxidation reactions which took place in the roasting process of stone coal was studied by thermodynamic analysis.Oxidation of organic carbon,pyrite and vanadium is spontaneous reaction,and organic carbon,pyrite are more easily oxidized than vanadium.Existence of organic carbon or pyrite in stone coal is not conducive to the oxidation of vanadium.Pre-removal of organic carbon or pyrite is favorable to the oxidation of vanadium.