中文摘要：

在KOH溶液中，芳甲酰肼（2）与cS2生成钾盐3；然后3在水合肼作用下经过环化、取代、肼解得3．巯基．4．氨基-5-苯基-4／／-1，2，4-三唑-乙酸酰肼（6），6再与CS2回流成环生成化合物5．（4．氨基-5-苯基-4肛1，2，4．三唑．3．硫烷基）-1，3，4-嗯二唑-2-硫醇（7），最后7与取代苄基氯反应得目标化合物A1-A6，与芳基甲醛反应得终产物B1-B15．目标化合物的结构均经’HNMR，”CNMR，IR，MS或HRMS确证结构．

英文摘要：

Compound 3 was prepared by reaction of benzohydrazide （2） with CS2 in the presence of KOH as solvent. This compound converted to （4-amino-5-phenyl-4H-1,2,4-triazol-3-ylsulfanyl）-acetic acid hydrazide （6） by the reactions of cycliza- tion, substitution and hydrazinolysis in the presence of hydrazine hydrate. Then 5-（4-amino-5-phenyl-4H-1,2,4-triazol- 3-ylsulfanylmethyl）-l,3,4-oxadiazole-2-thiol （7） were obtained by a refluence of compound 6 with CS2. This intermediate reacted with several substituted-benzyl chloride to afford a series of new derivatives A1 ~A6; in the meantime, reacted with several substituted-benzaldehyde to afford a series of new derivatives BlaB15. The structures of new products were charac- terized by means of IH NMR, 13C NMR, IR, MS or HRMS techniques.