在这份报纸,我们在 0.32.5 THz 的一个范围上使用了兆兆赫时间域光谱学(THz-TDS ) 调查形成固态氨基酸的 cocrystals,由磨氨基酸的二种不同类型的混合物形成了。为比较,我们准备了双层的样品,由没有磨擦,一起压二个单个部件的小团联合了。在地面混合样品,一些额外的吸收山峰出现了,与特征不同纯部件的山峰,而是这些山峰没出现在双层的样品。因此,在 THz 范围的这些额外的吸收山峰是 cocrystals 的唯一的特征。从我们的结果,我们相信 THz-TDS 是一种有希望的技术描绘 cocrystals。
In this paper, we used terahertz time-domain spectroscopy (THz-TDS) over a range of 0.3-2.5 THz to investigate the formation of solid-state cocrystals of amino acids, formed by grinding mixtures of two different kinds of amino acids. For comparison, we prepared dual-layer samples, combined by pressing two single-component pellets together without grinding. In the ground-mixture samples, some extra absorption peaks appeared, different from the characteristic peaks of the pure components, but these peaks did not appear in the dual-layer samples. Thus, these extra absorption peaks in the THz range are unique features of cocrystals. From our results, we believe that THz-TDS is a promising technique to characterize cocrystals.