CeO2储氧材料是汽车尾气净化催化剂中的重要载体,但因纯Ce02的热稳定性差,不适合在高温条件下使用,已被具有更高热稳定性的CeO2-ZrO2(CZ)材料所取代.随着汽车尾气排放标准的提高,对催化剂的要求越来越苛刻,对载体的织构性能、抗老化性能及低温氧化还原性提出了更高的要求.
CeO2-based oxygen materials were prepared with co-precipitation method and characterized via Brunauer-Emmet Teller(BET) method, X-ray diffraction(XRD) and temperature-programmed reduction(H2-TPR). This paper revealed that three CeO2-based oxygen storage materials are all forming homogeneous solid solution. Among the samples, CeO2-ZrO2-Al2O3(CZA) has the best textural properties and excellent thermal stability. The specific surface area and pore volume of aged CZA are 90 m2/g and 0.29 mL/g. We proposed a viewpoint: Al3+ might insert among the interspace of fluorite structure or highly dispersal in solid solutions.