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Size-dependent melting properties of Sn nanoparticles by chemical reduction synthesis
  • ISSN号:1003-6326
  • 期刊名称:《中国有色金属学报:英文版》
  • 时间:0
  • 分类:TB383[一般工业技术—材料科学与工程] X703[环境科学与工程—环境工程]
  • 作者机构:[1]Shanghai Key Laboratory of Modem Metallurgy and Materials Processing, Shanghai University, Shanghai 200072, China
  • 相关基金:Foundation item: Project(2006AA03Z339) supported by the National High-tech Research and Development Program of China; Project(50571057) supported by the National Natural Science Foundation of China; Project(08520740500) supported by Science and Technology
中文摘要:

有不同尺寸分发的听 nanoparticles 被作为减小代理人使用 NaBH4 用化学减小方法综合。比 100 nm 小的 Sn nanoparticles 少些被聚结并且显然不氧化了。这些综合 nanoparticles 的融化的性质被微分扫描热量测定学习。在 81, 40, 36 和 34 nm 的直径的 Sn nanoparticles 的融化的温度是 226.1, 221.8, 221.1 和 219.5 吗??

英文摘要:

Tin nanoparticles with different size distribution were synthesized using chemical reduction method by applying NaBH4 as reduction agent.The Sn nanoparticles smaller than 100 nm were less agglomerated and no obviously oxidized.The melting properties of these synthesized nanoparticles were studied by differential scanning calorimetry.The melting temperatures of Sn nanoparticles in diameter of 81,40,36 and 34 nm were 226.1,221.8,221.1 and 219.5?欲espectively.The size-dependent melting temperature and size-dependent latent heat of fusion have been observed.The size-dependent melting properties of tin nanoparticles in this study were also comparatively analyzed by employing different size-dependent theoretical melting models and the differences between these models were discussed.The results show that the experimental data are in accordance with the LSM model and SPI model,and the LSM model gives the better understanding for the melting property of the Sn nanoparticles.

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期刊信息
  • 《中国有色金属学报:英文版》
  • 中国科技核心期刊
  • 主管单位:中国科学技术协会
  • 主办单位:中国有色金属学会
  • 主编:黄伯云
  • 地址:中国长沙中南大学
  • 邮编:410083
  • 邮箱:f-xsxb@csu.edu.cn
  • 电话:0731-88830949
  • 国际标准刊号:ISSN:1003-6326
  • 国内统一刊号:ISSN:43-1239/TG
  • 邮发代号:42-317
  • 获奖情况:
  • 国家“双百”期刊,第二届全国优秀科技期刊评比二等奖,中国有色金属工业总公司优秀科技期刊一等奖
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  • 被引量:1159