为了满足CO2驱油施工设计和油藏模拟的需要,建立了一套完整的测量气体溶解度和扩散系数的实验装置。导出了包含这两个参数的气体压力~时间线性关系式。采用压力降落法在50℃、70℃、105℃温度和静态条件下,测定CO2-吉林红岗原油体系的压力随时间的变化,对所得曲线进行线性拟合,求得了实验条件下CO2在吉林红岗原油中的溶解度和扩散系数。讨论了平衡压力,压力、温度对溶解度和扩散系数的影响,得到了每一实验温度下溶解度~平衡压力、扩散系数-平衡压力线性拟合关系式。在105℃温度下,静态条件下的扩散系数值在10^-7m2/s数量级,而动态条件下(转速600r/min)则增至10^-6m2/s。图6表1参8
A set of experimental installation for measuring gas solubility ( S ) and diffusion coefficient ( DC ) was constructed for the purpose of project design and reservoir simulation of CO2 driving. A linear relationship between gas pressure and time duration and containing the two parameters was derived. The changes with time of pressure in CO2-Honggang's crude oil system were measured by using a pressure drop method under static conditions at temperature 50℃ ,70℃, and 105℃ ;the curves obtained were fitted linearly and the S and DC values of CO2 in the crude oil under experimental conditions were determined. The equilibrium pressure, the S and the DC influenced by pressure and temperature were discussed and linearly fitted equations of S and of DC vs equilibrium pressure were constructed for every experimental temperature. At 105℃ ,the static DC values were of magnititude 10 -7 m2/s and the dynamic ones( at stirring speed 600 r/min)--10^ -6 m2/s.