中文摘要：

采用间歇反应器，对液相环己酮氨肟化过程中TS一1分子筛的催化活性变化规律进行了考察，在失活原因分析的基础上建立失活动力学模型：rde=1.01×10^14exp（-1.17×10^5/RT）CA^0.76CB^0.82CC^0.38a^1.64,并对模型参数进行估值。

英文摘要：

The catalytic activity of TS-1 catalyst for ammoximation of cyclohexanone to cyclohexanone oxime was investigated in a batch reactor. The deactivation kinetic model of TS-1 catalyst for ammoximation was established on the bases of deactivation scheme analysis. Statistics analysis results showed that the deactivation kinetic model exhibited a stronger capacity for experimental data and a higher reliability. The model is rde=1.01×10^14exp（-1.17×10^5/RT）CA^0.76CB^0.82CC^0.38a^1.64.