欢迎您！东篱公司
退出
-
申报数据库
-
立项数据库
-
成果数据库
-
项目获奖数据库
中文摘要：
8-羟基喹啉是重要的金属离子鳌合剂,因金属离子与其结合后可阻断其分子内激发态质子转移（ESIPT）导致荧光增强而被广泛应用于荧光传感分子的设计中.但8-羟基喹啉对金属离子的选择性较差,研究多对喹啉母环结构修饰引入辅助配位基团以改善金属离子选择性,但以8-位羟基修饰的尝试偏少.本文以8-羟基喹啉不同结构修饰的衍生物为依据,评述其在重金属离子荧光增强型传感中的应用.
英文摘要：
8-Hydroxyquinoline is the second important chelator for metal ions.It is also extensively applied for construction of turn-on fluorescent chemosensors for metal ions in particular heavy transition metal ions,since the excited-state intramolecular proton transfer（ESIPT） process that makes it nonfluorescent is blocked upon metal ion coordination.Because of the relatively poor selectivity in the binding of 8-hydroxyquinoline with metal ions,structural modifications have been attempted on the aromatic ring to improve the metal selectivity,whereas those on the 8-OH group remain much less.In this article,we briefly review 8-hydroxyquinoline based turn-on fluorescent chemosensors for heavy transition metal ions,with an emphasis on the means of suppressing the fluorescence of the sensory molecules by design.
同期刊论文项目
同项目期刊论文
Anion Binding of N-(o-Methoxybenzamido)thioureas. Contribution of the Intramolecular Hydrogen Bond i
1,3,4-Oxadiazole based molecular system for multiple logic gates and switches triggered by metal ion
Anion binding in aqueous solutions by N-(Isonicotinamido)-N'-phenylthiourea-based simple synthetic n
Oxidative cyclization of N-acylhydrazones. Development of highly selective turn-on fluorescent chemo
Photoluminescence of CdTe nanocrystals modulated by methylene blue and DNA. A label-free luminescent
Anion-triggered substituent-dependent conformational switching of salicylanilides. New hints for und
1,6-Bis(4-methox phenylsulfanyl) perchlorofluoranthene: A molecule with sandwiched mu-mu stacking li
Supramolecular aggregation/disaggregation-based molecular sensing: a review focused on investigation
Anion Binding of N-(o-Methoxybenzamido)thioureas: Contribution of the Intramolecular Hydrogen Bond i
Ratiometric Fluorescent Chemosensor for Hg2+ Based on Heptamethine Cyanine Containing a Thymine Moie
Enhanced saccharide sensing based on simple phenylboronic acid receptor by coupling to Suzuki homoco
A facile and general approach for the synthesis of fluorescent silica nanoparticles doped with inert
Metal-Metal-Interaction-Facilitated Coordination Polymer as a Sensing Ensemble: A Case Study for Cys
Ultrasensitive Pb(2+) detection based on fluorescence resonance energy transfer (FRET) between quant
Fluorescent sensing of anions based on excited state intramolecular proton transfer in N-(3-hydroxy-
Sensing hydrogen peroxide involving intramolecular charge transfer pathway: A boronate-functioned st
Ring Expansion of Spiro-thiolactam in Rhodamine Scaffold: Switching the Recognition Preference by Ad
A highly sensitive and selective antioxidant probe based on a bi-modally functionalized conjugated p
Ultrasensitive detection of phenolic compounds based on a spin-labeled luminescent lanthanide comple
期刊信息
位置：