用为在在 266 nm 的 acetonitrile 答案的碳二硫化物的二光子光致离解的学习的激光闪光 photolysis/transient 吸收技术,在有在 260 nm 的最大的吸收的 240370 nm 和随后的分离产品 CS ( 3 )以内的 Rydberg 州的 CS2 ( 6sg )的短暂紫外力的吸收光谱直接被观察。在氮和氧的 CS (3 ) 的一生浸透了溶液也在我们的实验被学习。
Using laser flash photolysis/transient absorption technique for the study of two photon photodissociation of carbon disulfide in acetonitrile solution at 266 nm, the transient UV-Vis absorption spectrum of Rydberg state CS2 (6sσg) within 240-370 nm and subsequent dissociation product CS (α^3П) with the maximum absorption at 260 nm were directly observed. The lifetime of CS (α^3П) in the nitrogen and oxygen saturated solution is also studied in our experiment.