设计合成了两种新型含强供电基目的三苯胺均二苯乙烯类化合物,并通过IR、MS、NMR进行了结构表征,用紫外吸收光谱、荧光发射光谱、循环伏安法(CV)等手段研究了它们的光电性能,分析了它们的电化学行为,计算出其电离势(P1)分别为5.41和5.54eV,带隙(E)分别为2.72和2.74eV,结果表明强供电子基团的引入大大增强了荧光量子效率和空穴的注入传输能力。
Two novel electro-donor triphenylaminostilbene-like derivations were synthesized and their structure were confirmed by IR, N MR, MS. The properties of photo-electricity were characterized by UV-vis spectra,photoluminescent spectra,cyclic voltammeter and the electrochemistry behavior were analyzed. Their ionization potentials (PI) were 5.41eV,and 5.54,band gaps (E8) were 2.72,2. 74eV respectively, indicating that both electroluminescence and hole-transporting property were enhanced by electro-donor substituents.