制备非离子表面活性剂P123(聚氧乙烯-聚氧丙烯-聚氧乙烯(PEO-PPO-PEO))、十二烷基硫酸钠(SDS)和水形成的3组分体系液晶并研究其性质。采用偏光显微镜(POM)及小角X射线散射技术(SAXS),观测体系内各组分不同质量分数时的双折射现象和液晶织构,并确定样品相态。结果表明:当wP123=w(H2O)=45%,wSDS=10%时,在P123/SDS/H2O3组分体系中可以形成六角相;当wP123=63%,w(H2O)=27%,wSDS=10%时,P123/SDS/H2O 3组分体系中可以形成立方相。
Three-components liquid crystal system is formed by mixing nonionic surfactant P123(poly(ethylene oxide-poly propylene-poly(ethylene oxide(PEO-PPO-PEO),sodium dodecyl sulfate(SDS),and its properties are investigated.Hexagonal liquid crystal phase is identified in wP123=w(H2O)=45%,wSDS=10% system,and cubic liquid crystal phase is found in wP123=63%,w(H2O)=27%,wSDS=10% systems by using polarized optical microscopy and small-angle X-ray scattering techniques.