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Polyethylene glycol-supported ionic liquid as a highly efficient catalyst for the synthesis of propylene carbonate under mild conditions
  • ISSN号:1004-9533
  • 期刊名称:《化学工业与工程》
  • 时间:0
  • 分类:TQ223.121[化学工程—有机化工] O623.662[理学—有机化学;理学—化学]
  • 作者机构:[1]Key Laboratory for Green Chemical Technology of State Education Ministry, School of Chemical Engineering & Technology, Tianjin University, Tianjin 300072, China
  • 相关基金:Acknowledgements The work was supported by the National Natural Science Foundation of China (Grant No. 21076152), the Special Research Fund for the Doctoral Program of Higher Education of China (No. 2100032110018) and the Program of Introducing Talents of Discipline to Universities, China (No. B06006).
中文摘要:

到形式丙烯碳酸盐(PC ) 的丙烯和 CO2 的联合反应被离子的液体(IL ) 支持聚乙烯乙二醇(木钉) covalently 一定。支持的离子的液体,有酸、基本的部件,证明了是为在温和条件下面的 PC 合成的活跃催化剂。不同阳离子和阴离子,反应温度, CO2 压力,和反应时间的效果被调查。在催化剂的酸组在反应起一个重要作用,这被表明。与这个系统,高 PC 收益(95%) 在温和条件下面被完成(3.0 MPa, 120

英文摘要:

The coupling reaction ofpropylene and CO2 to form propylene carbonate (PC) was promoted by an ionic liquid (IL) covalently bound to polyethylene glycol (PEG). The supported ionic liquid, which has both acidic and basic components, proved to be an active catalyst for PC synthesis under mild conditions. The effects of different cations and anions, reaction temperature, CO2 pressure, and reaction time were investigated. It was demonstrated that the acid group in the catalyst plays an important role in the reaction. With this system, a high PC yield (95%) was achieved under mild conditions (3.0 MPa, 120℃ and 4 h) without a co-solvent. In addition, the catalyst was readily recovered and reused. Based on the experimental results, a plausible mechanism for the catalyst was proposed.

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期刊信息
  • 《化学工业与工程》
  • 中国科技核心期刊
  • 主管单位:天津渤海化工集团有限责任公司
  • 主办单位:天津大学 天津市化工学会
  • 主编:马新宾
  • 地址:天津大学化工学院
  • 邮编:300350
  • 邮箱:hgbjb@tju.edu.cn
  • 电话:022-27406054
  • 国际标准刊号:ISSN:1004-9533
  • 国内统一刊号:ISSN:12-1102/TQ
  • 邮发代号:18-156
  • 获奖情况:
  • 天津市一级学术期刊,第六届全国石油和化工行业优秀期刊(一等奖)
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),波兰哥白尼索引,美国剑桥科学文摘,中国中国科技核心期刊
  • 被引量:7373