到形式丙烯碳酸盐(PC ) 的丙烯和 CO2 的联合反应被离子的液体(IL ) 支持聚乙烯乙二醇(木钉) covalently 一定。支持的离子的液体,有酸、基本的部件,证明了是为在温和条件下面的 PC 合成的活跃催化剂。不同阳离子和阴离子,反应温度, CO2 压力,和反应时间的效果被调查。在催化剂的酸组在反应起一个重要作用,这被表明。与这个系统,高 PC 收益(95%) 在温和条件下面被完成(3.0 MPa, 120
The coupling reaction ofpropylene and CO2 to form propylene carbonate (PC) was promoted by an ionic liquid (IL) covalently bound to polyethylene glycol (PEG). The supported ionic liquid, which has both acidic and basic components, proved to be an active catalyst for PC synthesis under mild conditions. The effects of different cations and anions, reaction temperature, CO2 pressure, and reaction time were investigated. It was demonstrated that the acid group in the catalyst plays an important role in the reaction. With this system, a high PC yield (95%) was achieved under mild conditions (3.0 MPa, 120℃ and 4 h) without a co-solvent. In addition, the catalyst was readily recovered and reused. Based on the experimental results, a plausible mechanism for the catalyst was proposed.