中文摘要：

合成了meso-四（4-二茂铁甲酰氧基苯基）卟啉及其锌配合物．采用紫外-可见吸收光谱、稳态和时间分辨荧光光谱以及开孔Z-扫描等实验方法对其线性与非线性光学性质进行研究．结果表明二茂铁的引入对卟啉的吸收几乎未产生影响，但是却使卟啉的荧光发生了强烈的猝灭，荧光寿命缩短．说明在基态二茂铁与卟啉之间未发生作用，而在激发态发生了较强的电子和能量的传递．与相应的meso-四（4-苯甲酰氧基苯基）卟啉及其锌配合物相比，meso-四（4-二茂铁甲酰氧基苯基）卟啉及其锌配合物的反饱和吸收性能降低，但是非线性光学性质仍然优于性能优良的富勒烯C60.

英文摘要：

meso-Tetra（4-ferrocenylcarbonyloxyphenyl）porphyrin and its zinc（II） complex were synthesized. Their linear and nonlinear optical properties were investigated using UV-Vis absorption spectra, steady state and time-resolved fluorescence spectra and open-aperture Z-scan measurements. The results indicated that the introduction of ferrocene to porphyrin had not affected the absorption spectra of porphyrin, but quenched the fluorescence intensively and shortened the fluorescence life-times of porphyrin, which indicated that there was almost no interaction between porphyrin and ferrocene in the ground state, but a strong interaction in the excited state. The reverse saturable absorptions of meso-tetra（4-ferrocenylcarbonyloxyphenyl）- porphyrin and its zinc（II） complex were weaker than those of the corresponding meso-tetra（4-benzoyloxyphenyl）porphyrin and its zinc（II） complex, but were stronger than that of fullerene C60 with excellent performance.