以(R,R)-N,N′-[2,2′-双(次氨基次甲基)]双[4-(亚甲基-N-吗啉基)-6-叔丁基)苯酚]-1,2-二苯基乙二胺为配体合成了6种SalenCoX配合物,其轴向离子分别为氯、溴、硝酸根、叠氮根、三氟醋酸根及四氟化硼根。利用1HNMR、13CNMR、FT-IR、UV-Vis、循环伏安法、ESI-MS和元素分析对配体及配合物进行了表征,证明了所得产物与目标化合物一致。
A series of cobalt Salen complexes,N,N′-bis(salicylidene)-1,2 phenylenediamino CoX(X=Cl,Br,NO3,CF3COO,BF4 and N3)(SaleneCoX),were prepared and characterized by 1HNMR,13CNMR,FT-IR,UV-Vis,cyclic voltammograms,ESI-MS spectroscopy and elemental analysis.The results demonstrated that the target compounds were successfully synthesized.