超声条件下,在乙醇分散的3-氨丙基三乙氧基硅烷(APTES)功能化的磁性Fe3O4纳米粒子和氯铂酸的混合溶液中,滴加水合肼成功地制备了磁性Fe3O4/Pt复合纳米粒子。采用紫外吸收可见光谱(UV-Vis),电子能谱仪(EDS),透射电子显微镜(TEM),光电子能谱(XPS),超导量子干涉仪(SQUID)等方法对复合粒子的形态、结构、组成以及磁学性质进行了表征。结果表明:在此条件下制得的复合粒子粒度在50nm左右,室温下磁化强度可达17.2(A·m2)/kg。
Magnetic composite nanoparticles Fe3O4/Pt were prepared via ultrasonic irradiation to the mixed solution of hexachloroplatinum acid hydrate solution and(3-aminopropyl)triethoxysilane(APTES)-coated Fe3O4 nanoparticles and subsequent dropping addition of hydrozine hydrate.The morphology,microstructure,composition and magnetic properties of the Fe3O4/Pt nanoparticles were characterized by ultraviolet-visible spectroscopy(UV-Vis),energy dispersive spectroscopy(EDS),transmission electron microscopy(TEM),X-ray photoelectron spectroscopy(XPS) and superconducting quantum interference device(SQUID) magnetometry.Results show that Fe3O4/Pt nanoparticles obtained under the conditions possess saturation magnetization intensity of about 17.2(A·m2)/kg,and their average diameter is about 50 nm.