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电化学诱导聚合甲基丙烯酸膜及葡萄糖酶电极制备
  • ISSN号：1006-3471
  • 期刊名称：《电化学》
  • 时间：0
  • 分类：TQ035[化学工程]
  • 作者机构：[1]厦门大学化学化工学院化学系,福建厦门361005
  • 相关基金：国家自然科学基金（项目编号：20833005）资助.
作者： 王胜[1], 雷瑛[1], 时康[1]
关键词： 电化学还原诱导, 自由基聚合, 水凝胶膜, 甲基丙烯酸, 葡萄糖氧化酶电极, electrochemically induced, free radical polymerization, amperometric glucose biosensor, hydrogel layer, methacrylic acid
中文摘要：

应用电化学还原诱导自由基聚合方法在金基底上聚合甲基丙烯酸水合凝胶膜。聚合过程为：在中性缓冲溶液中，由电还原过硫酸根离子产生的硫酸根自由基，激发甲基丙烯酸发生自由基聚合反应，形成超薄的水合凝胶膜；同时也可将葡萄糖氧化酶包敷于膜内，制成葡萄糖氧化酶电极。

英文摘要：

Electrochemically induced free radical polymerization of methacrylic acid was preliminarily investigated. Based on the electrochemical reduction of persulfate anion in phosphate buffer （pH 7.0） solution, the free radical polymerization of methacrylic acid was initiated to generate an ultrathin and biocompatible hydrogel layer on the gold electrode. At the meantime, glucose oxidase could be immobilized within the hydrogel film in the polymerization process. The resulting biosensor displayed an attractive performance.

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期刊信息
  • 《电化学》
  • 北大核心期刊（2011版）
  • 主管单位:中国科学技术协会
  • 主办单位:中国化学会 厦门大学
  • 主编：孙世刚
  • 地址：厦门大学D信箱
  • 邮编：361005
  • 邮箱：dianhx@xmu.edu.cn
  • 电话：0592-2181469
  • 国际标准刊号：ISSN：1006-3471
  • 国内统一刊号：ISSN：35-1172/O6
  • 邮发代号:34-61
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘（网络版）,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊（2004版）,中国北大核心期刊（2008版）,中国北大核心期刊（2011版）,中国北大核心期刊（2014版）
  • 被引量:4569