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Confined growth of Li4Ti5O12 nanoparticles in nitrogendoped mesoporous graphene fibers for high-performance lithium-ion battery anodes
  • ISSN号:0253-9837
  • 期刊名称:《催化学报》
  • 时间:0
  • 分类:TQ342.743[化学工程—化纤工业] TM912.2[电气工程—电力电子与电力传动]
  • 作者机构:[1]State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China, [2]Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, TsinghuaUniversity, Beijing 100084, China, [3]Department of Chemical and Biomolecular Engineering, University of California, Los Angeles, CA 90095, USA
  • 相关基金:This work was supported by National Natural Science Foundation of China (Nos. 21306102 and 21422604), and partially supported by Science Foundation of China University of Petroleum, Beijing (No. 2462013YJRC028).
中文摘要:

有电气化学的活动的 Nanomaterials 总是正在受不了聚集,特别地在高温度的合成过程期间,它将导致减少的精力存储性能。这里,层次地组织了锂 titanate/nitrogen-doped 多孔的 graphene 纤维 nanocomposites 被使用李 4 Ti 5 在做氮的 mesoporous graphene 纤维(NPGF ) 的 O 12(LTO ) nanoparticles。有一致毛孔结构的 NPGF 作为模板被使用招待 LTO 先锋,在 800 点由高温度的处理列在后面

英文摘要:

Nanomaterials with electrochemical activity are always suffering from aggregations, particularly during the high-temperature synthesis processes, which will lead to decreased energy-storage performance. Here, hierarchically structured lithium titanate/nitrogen-doped porous graphene fiber nanocomposites were synthesized by using confined growth of Li4Ti5O12 (LTO) nanoparticles in nitrogen-doped mesoporous graphene fibers (NPGF). NPGFs with uniform pore structure are used as templates for hosting LTO precursors, followed by high-temperature treatment at 800 ~C under argon (Ar). LTO nanoparticles with size of several nanometers are successfully synthesized in the mesopores of NPGFs, forming nanostructured LTO/NPGF composite fibers. As an anode material for lithium-ion batteries, such nanocomposite architecture offers effective electron and ion transport, and robust structure. Such nanocomposites in the electrodes delivered a high reversible capacity (164 mAh.g-1 at 0.3 C), excellent rate capability (102 mAh-g-1 at 10 C), and long cycling stability.

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期刊信息
  • 《催化学报》
  • 北大核心期刊(2011版)
  • 主管单位:中国科学院
  • 主办单位:中国化学会 中国科学院大连化学物理研究所
  • 主编:李灿 张涛
  • 地址:大连市沙河口区中山路457号
  • 邮编:116023
  • 邮箱:chxb@dicp.ac.cn
  • 电话:0411-84379240
  • 国际标准刊号:ISSN:0253-9837
  • 国内统一刊号:ISSN:21-1195/O6
  • 邮发代号:8-93
  • 获奖情况:
  • 第三届国家期刊奖提名奖,中国科协精品科技期刊示范项目
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  • 俄罗斯文摘杂志,美国化学文摘(网络版),荷兰文摘与引文数据库,美国工程索引,美国剑桥科学文摘,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:19199