施威特曼石普遍存在于含大量SO42-的酸矿水中,其表面吸附的SO42-使得该矿物具有强吸附重金属离子的能力,可用于处理重金属离子污染。实验通过在不同浓度Cu2+溶液中合成施威特曼石时发现,Cu2+与施威特曼石的共沉淀量较低,FTIR分析表明Cu2+与施威特曼石的羟基发生反应。开展施威特曼石吸附Pb2+的实验,结果表明施威特曼石对Pb2+的吸附符合Langmuir模型,施威特曼石吸附Cu2+和Pb2+后出现1545.4 cm-1和1435.0 cm-1(Cu2+)两个吸收峰,可能是施威特曼石孔道表面形成了三元配合物。在241×10-6的初始浓度(与尾矿孔隙水的Pb2+含量相近)下有61.4%的Pb2+去除率,显示了较好的环境修复价值。
Schwertmannite is a pervasive mineral in SO42-rich acid mine drainage(AMD).Abundant surface-absorbed SO42-anions enhance the adsorption of heavy metal ions,thus schwertmannite can be used in remediation of heavy metals contamination.In this study,by synthesizing schwertmannite under a range of concentration of Cu2+,it is disclosed in FTIR analysis that Cu2+ co-precipitates with schwertmannite,and there is a interaction between Cu2+ and-OH of schwertmannite.The process of Pb2+ adsorption by schwertmannite is well consistent with the Langmuir model.Two FTIR peaks of 1545.4 cm-1 and 1435.0 cm-1 are assigned to the formation of ternary complex on the internal surface of schwertmannite.Under Pb2+ concentration of 241×10-6(similar to the concentration of AMD),61.4% of Pb2+ can be removed by adsorption,suggesting potential applications in remediation.