本文在低温太阳热能与CH3OH-Fe2O3化学链燃烧相结合控制CO2分离动力系统的基础上,进一步探讨了低温太阳热能品位提升的内在规律,分别揭示出辐照强度与CH3OH—Fe2O3反应特性、低温太阳热能品位提升的关联关系。本文采用溶胶凝胶法制作了Fe2O3反应颗粒,在热重反应器中进行了模拟太阳热能与甲醇化学链实验的初步研究,通过电镜,分析了反应前后金属氧化物的表面形貌特征。研究成果将为低温太阳热能与化学链燃烧整合能量释放新机理的研究提供理论依据和基础实验数据。
Based on the proposed thermal cycle with inherent CO2 separation using methanol-chemical looping combustion by low-grade solar thermal energy, this paper discussed the principle of upgrading low-temperature solar thermal energy, and disclosed the relationships among the radiation intensity, the reactivity of CH3OH-Fe2O3, and the energy-level upgrade of solar thermal energy. The experimental study on the reaction of CH3OH-Fe2O3 was carried out by a thermogravimetric analyzer (TGA). The Fe2O3 particles were prepared with impregnation techniques, and the surfaces configures of the particles before and after reaction were analyzed by the scanning electron microscope (SEM). The promising results obtained here will provide the useful theory and experimental data for the energy conversion principle of the energy system integrating methanol-chemical looping combustion and low-temperature solar thermal energy.