壳聚糖具有成膜性、抗菌性及无毒无害等多种优良性能,以壳聚糖(CTS)为主要在膜材料,并辅以月桂酸钠改性的纳米TiO2,制备了一种新型安全无毒的涂膜剂壳聚糖/纳米TiO2复合涂膜,与农药(P)原药混合后,制得壳聚糖-纳米TiO2-农药复合膜剂型(CTS—TiO2-P)。分别用配置好的P(对照),壳聚糖-农药(CTS—P)及CTS—TiO2-P溶液喷施农作物,用GC—FPD)(气相色谱-火焰光度检测器)对3种溶液喷施后在植株上的农药残留量动态情况进行检测和比较,试验结果表明:当溶液中农药的质量分数为0.04%,复合膜溶液中壳聚糖的质量分数为2%,纳米TiO2质量分数为0.03%时,复合膜剂型农药在植株上的长效性比单纯农药的长效性明显提高,而且添加了纳米TiO2的复合膜农药效果优于单纯的壳聚糖-农药复合膜,药效持续时间由45天延长到90天以上,这样可以减少农药的施药次数;同时,在达到相同的杀虫效果的条件下,可以节约1/2的农药用量,这对减少农药资源的浪费、降低生产成本及防治环境污染具有较好的作用。
Chitosan has many excellent properties such as film - forming, non - toxic, antibacterial, choosing chitosan as the main film -forming material, supplemented nano -TiO2 modified by Sodium Laurate, prepared a new type of safe, non - toxic film called CTS - TiO2 composite film, then mixed with Pesticide(P) prepared a composite film called CTS- TiO2 -P,the crops were sprayed by the prepared solution P( contrast), CTS - P and CTS - TiO2 - P separately, the dynamic test results of CTS - TiO2 - P, CTS -P,P on plant were detected and compared by GC -FPD. The results showed that when the ratio of P,chitosan and TiO2 was 0.04% ,2% ,0.03% separately,the long- term effects of pesticide compound membrane were significantly longer than that of the pure pesticide, composite membrane pesticide formulations added nano - TiO2 were superior to CTS - P composite membrane, the efficacy of composite membrane pesticide formulations extended from 45 d to CTS -P composite membrane, the efficacy of composite membrane pesticide formulations extended from 45 d to 90 d and above. Meanwhile , at the condition of reaching the same effect of killing inserts, pesticide usage can be saved 1/2, it has better effect to reduce the waste of peaticide resources, production costs and to prevent and control environmental pollution.