中文摘要：

以对苯二酚和双酚A为原料,分别与4-硝基邻苯二腈在氮气保护的碱性环境下,合成了两种双（邻苯二腈）类化合物：4,4′-（对苯二氧）双（邻苯二腈）（化合物A）和4,4′-{[丙烷-2,2-二基双（1,4-对苯）]双氧代}双（邻苯二腈）（化合物B）.考察了不同反应条件对产物产率的影响,得到了最佳制备工艺条件：碱性环境为分散在DMF中的无水碳酸钾,反应物摩尔配比为2.4∶1（化合物A）和2.3∶1（化合物B）,反应温度为55℃,反应时间为6h.对化合物A和B分别进行紫外光谱和红外光谱表征,确定得到了目标产物.

英文摘要：

Two kinds of diphthalates nitrile compounds 4′-（1,4-phenylenebis（oxy））diphthalonitrile（Compound A）,and 4,4′-{[propane-2,2-diylbis（4,1-phenylene）]bis（oxy）}diphthalonitrile（compound B）were obtained by using hydroquinone and 2,2-bis（4-hydroxyphenyl）propane to react with 4-nitro phthalates nitrile in alkaline media at a nitrogen atmosphere,respectively.The efforts of reaction conditions on yields were investigated,and the optimum reaction conditions were obtained：alkaline condition was anhydrous potassium carbonate distracted in DMF,the molar ratios of reactants were 2.4∶1（compound A）and 2.3∶1（compound B）,optimal reaction temperature was 55 oC and reaction time was 6h.UV-Visible spectroscopy and Infrared（IR）were used to characterize A and B,and the products were obtained successfully.