中文摘要：

利用微波技术合成了配合物[Gd2（Gly）6（H2O）4】（ClO4）6（H2O）5，进行了化学成分分析、红外表征和热重分析．应用X衍射仪测定其晶体结构，该晶体为一维链结构，属三斜晶系，P1^-空间群，晶胞参数：a=1．1569（17）nm，b=1．4138（2）nm，c=1．5642（2）nm，α=96．910（2）°，β=102．735（2）°，γ=105．512（2）°，V=2．3606（6）nm^3，Z=2，Dc=2．144g·cm^-3．采用精密溶解-反应量热计，通过设计热化学循环，计算出了该配合物的标准摩尔生成焓为-（7960．73±3．23）kJ·mol^-1．

英文摘要：

The complex [Gd2（Gly）6（H2O）4]（ClO4）6（H2O）5 was synthesized by a microwave technology characterized by IR spectra and a TG-DTG technique. The crystal structure of the complex was determined by an X-ray diffraction method. The crystal is a 1D chain structure, which belongs to a triclinic system with space group P1^-, and cell parameters： a=1.1569（17）nm,b=1.4138（2）nm,c=1.5642（2）nm,α=96.910（2）°,β=102.735（2）°,γ=105.512（2）°,V=2.3606（6）nm^3,Z=2,and Dc=2.144g·cm^-3. By isoperibol solution-reaction calorimetry, the standard molar enthalpy of formation of the complex was determined to be -（7960.73 ± 3.23） kJ·mol^-1.