本文利用常规方法合成了[ZnBIX(CNAC)2]n·nH2O,(BIX为1,4-(二亚甲基苯)二咪唑(CNAC为肉桂酸)。并通过元素分析,热重分析,荧光分析和X-射线单晶衍射仪对其进行结构表征。该化合物属于三斜晶系,空间群为P-1,α=10.228(2)A,b=10.831(2)A,c=13.416(3)A,α=84.972(4)°β8=86.295(3)°γ=77.499(4)°V=1443.8(5)A^3,C32H30N4O5Zn,Mr=615.97,Dc=1.417g·cm^-3,F(000)=640,Z=2,R1=0.0443,WR2=0.0984。
An interest compound [Zn (BIX)(CNAC)n (H2O)] (BIX=1-(4-((1H-imidazol-1-yl)methyl) benzyl)-1H-imidazole), CANC=Cinnamic acid) is synthesized by using conventional method and structurally characterized by elemental analysis, thermogravimetric analysis, IR specatrum, and single-crystal X-ray diffraction. Compound crystallizes in the triclinic system, space group P-l, with A=10.228(2)A, b=10.831(2)A, c=13.416(3) A. α=84.972(4)°, fl=86.295 (3)°, γ=77.499(4)°, V=1443.8(5)A3, C32H30N4O5Zn, Mr=615.97,Dc=1.417g·cm^-3,F (000)=640, Z=2, the final R=0.0443 and wR=0.0984. The compound 1 has a 1D S-type chain structure, and generates an infinit 2-D layer with intermolecular hydrogen bonds.