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Experimental study of separation of ammonia synthesis vent gas by hydrate formation
  • 时间:0
  • 分类:TE642[石油与天然气工程—油气加工工程] TQ226.37[化学工程—有机化工]
  • 作者机构:[1]State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China
  • 相关基金:The financial support received from the National Natural Science Foundation of China (20476058, 20676146) and Ministry of Science and Technology of China (2006AA09A208, 2009CB219504) and Specialized Research Fund for the Doctoral Program of Higher Education (20070425001) are gratefully acknowledged.
  • 相关项目:天然气水合物传质传热性能及稳定性研究
中文摘要:

甲烷水合物形成上的 Termodynamic 数据为氨合成升级面对氨是很重要的发泄煤气的使用水合物形成。这份报纸在分离上面对氨和煤气液体的比率和温度的效果集中于甲烷水合物的形成条件由水合物形成发泄气体。为在从 1% ~ 5 % 的一个氨鼹鼠集中范围以内的甲烷水合物的平衡数据被获得。试验性的结果显示氨在水合物形成上有禁止的效果。越高氨集中,越多 higher 是为甲烷水合物形成的压力 reguired 将是。主要试验性的结果证明当到液体的气体的体积比率是 80:1,温度是 283.15 K 时,总计鼹鼠部分(H2+N2 ) 在气体,阶段能到达 96.9 % 。

英文摘要:

Termodynamic data on methane hydrate formation in the presence of ammonia are very important for upgrading of ammonia synthesis vent gas using hydrate formation. This paper is focused on the formation conditions of methane hydrate in the presence of ammonia and the effects of gas-liquid ratio and temperature on the separation of vent gas by hydrate formation. Equilibrium data for methane hydrate within an ammonia mole concentration range from 1% to 5 % were obtained. The experimental results indicated that ammonia has an inhibitive effect on hydrate formation. The higher the ammonia concentration, the higher is the pressure reguired for methane hydrate formation would be. The primary experimental results showed that when volume ratio of gas to liquid was 80:1 and temperature was 283.15 K, total mole fraction of (H2+N2) in gas phase could reach 96.9 %.

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