中文摘要：

研究制备了苝酰亚胺——手性表面活性剂复合物N,N′-双（2-（季铵基乙撑））-3,4,9,10-苝二酰亚胺-双（（3R）-3,7-二甲基辛基-6-乙烯基）磷酸盐,详细研究了其在乙醇/正己烷,乙醇/正辛烷溶液中的自组装行为及组装机理。结果表明,该复合物在乙醇/正己烷溶液中组装为纳米管,在乙醇/正辛烷溶液中组装为纳米带。对其组装机理研究表明,该分子在溶液中组装为不同形态的纳米结构是π-π相互作用,疏水作用及手性诱导等多种作用力协同作用的结果.

英文摘要：

The complex N,N′-bis（2-（tri methylammonium）ethylene）-perylene-3,4,9,10-tetracarboxyldii mide-bis （（3R）-3,7-di methyloct-6-enyl） phosphate（PTCDI-BDP） was synthesized,and its self-assembly behaviours in ethanol/n-hexane and ethanol/n-octane binary solutions were studied in detail.It is believed that PTCDI-BDP molecules self-assemblied into nanotubes in ethanol/n-hexane and nanobelts in ethanol/n-octane could be ascribed to the cooperative actions including theπ-πstacking,hydrophobic interactions and chirality.