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乙二醛制备单宁基胶粘剂的研究
  • ISSN号:1004-2849
  • 期刊名称:《中国胶粘剂》
  • 时间:0
  • 分类:TQ432.9[化学工程]
  • 作者机构:[1]西南林业大学,云南省木材胶粘剂及胶合制品重点实验室,云南昆明650224, [2]贵州大学林学院,贵州贵阳550025, [3]江西省高安二中,江西宜春330800
  • 相关基金:云南省科技厅国际合作项目(2014IA017); “十二五”国家科技支撑计划项目(2015BAD14B03); 云南省中青年学术带头人后备人才项目(2011HB024)
中文摘要:

以栲胶为原料、非挥发性无毒乙二醛为固化剂和PF(酚醛树脂)为键桥增长剂,制备了单宁基胶粘剂,并考察了乙二醛掺量对单宁基胶粘剂适用期、耐沸水胶接强度等影响。研究结果表明:乙二醛或甲醛(F)作为单宁基胶粘剂的固化剂,前者的环保性优于后者;当w(乙二醛)=10.0%(相对于单宁质量而言)时,制备的单宁基胶粘剂具有相对最大的耐沸水胶接强度;以乙二醛或F为固化剂制备的单宁基胶粘剂,前者的耐沸水胶接强度虽低于后者,但仍满足GB/T 9846.3—2004标准中Ⅰ类胶合板的指标要求,并且前者的施胶性能和适用期明显优于后者。

英文摘要:

With tannin extract as raw material, non-volatile and non-toxic glyoxal as curing agent and PF(phenolic resin) as a chain bridge agent, the tannin base adhesive was prepared, and the influences of glyoxal contents on working life, and bonding strength at boiling water resistance of tannin base adhesive were investigated. The research results showed that when glyoxal or formaldehyde (F) were used as curing agent of tannin base adhesive, the environment friendly property of the former was better than that of the latter. The prepared tannin base adhesive had the relatively maximal bonding strength at boiling water resistance when mass fraction of glyoxal was 10.0% in tannin. When the tannin base adhesives were prepared by glyoxal or F as curing agent, so the bonding strength at boiling water resistance of the former was lower than that of the latter, but it could still meet the index requirement of I-type plywood in GB/T 9846.3-2004 standard, and the sizing property and working life of the former were obviously better than those of the latter.

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期刊信息
  • 《中国胶粘剂》
  • 中国科技核心期刊
  • 主管单位:上海华谊(集团)公司
  • 主办单位:上海市合成树脂研究所 中国胶粘剂工业协会 全国粘合剂信息站
  • 主编:刘芳
  • 地址:上海市詛路西路1251号
  • 邮编:201702
  • 邮箱:gxlj@chinajournal.net.cn
  • 电话:021-64821610
  • 国际标准刊号:ISSN:1004-2849
  • 国内统一刊号:ISSN:31-1601/TQ
  • 邮发代号:4-454
  • 获奖情况:
  • 华东地区优秀科技期刊(2012年)、上海市科技期刊...
  • 国内外数据库收录:
  • 美国化学文摘(网络版),中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:7974