位置:成果数据库 > 期刊 > 期刊详情页
活性炭上NO和SO2的常温吸附特性研究
  • ISSN号:1004-4248
  • 期刊名称:《煤炭转化》
  • 时间:0
  • 分类:TQ424.1[化学工程]
  • 作者机构:[1]昆明理工大学环境科学与工程学院,昆明650500
  • 相关基金:国家自然科学基金资助项目(20907018,21177051)、教育部博士点新教师基金资助项目(20095314120008)和云南省中青年学术和技术带头人后备人才项目(2008PY009).
中文摘要:

通过吸附穿透曲线和吸附容量,考察了两种活性炭吸附剂在不同气氛条件下SO2和NO的常温吸附性能.结果表明,无氧条件下,活性炭对NO吸附能力较弱;有氧时,O2可促进NO在活性炭上的吸附转化;无氧条件下,活性炭吸附SO2的性能远远强于吸附NO;O2的存在均可提高两种活性炭对No和SO2的吸附能力.预吸附NO形成的某些NOx物种可促进SO2吸附.SO2对NO的吸附有明显抑制作用.同时吸附时,SO2和NO不会单独占据同一活性中心,即S02与NO可能有共同的吸附位,并形成新的吸附态中间产物.且比较两种活性炭的常温吸附性能,椰壳活性炭强于煤质活性炭.

英文摘要:

The characters of two types of activated carbon absorbents in the processes of NO and SO2 adsorption at room temperature were investigated by adsorption breakthrough curve and adsorption capacity in this work. The results show that, in the absence of O2, the adsorptive capability for NO of these two activated carbon absorbents are extremely weak. Obvious improvement of NO adsorption could be observed in the adsorption process under the O2-attendance conditions. For individual component adsorption, the two sorbents show a higher adsorption capacity in SO2 than in NO, and the presence of O2 could promote the adsorption both NO and SOs. Coal activated carbon has better capacity of absorbing SO2 and the process might be promoted by certain species produced by NO pre-adsorption. SO2 has an inhibiting effect on NO adsorption. In the simultaneous adsorption of NO-SO2-05, NO and SOs may not occupy the same active site independently. It means that new adsorbed intermediate species may formed during the co-adsorption of NO-SO2-O2. The coconut shell activated carbon performed better than the coal activated carbon in the co-adsorption process at room temperature.

同期刊论文项目
期刊论文 35 会议论文 1
同项目期刊论文
期刊信息
  • 《煤炭转化》
  • 北大核心期刊(2011版)
  • 主管单位:太原理工大学
  • 主办单位:太原理工大学
  • 主编:李晋平
  • 地址:山西太原市迎泽西大街79号理工大北区
  • 邮编:030024
  • 邮箱:ebcc@tyut.edu.cn
  • 电话:0351-6010162
  • 国际标准刊号:ISSN:1004-4248
  • 国内统一刊号:ISSN:14-1163/TQ
  • 邮发代号:22-44
  • 获奖情况:
  • 第三、四、五届华北地区十佳期刊,1990-2001年连续17次被评为华北地区优秀期刊、山...,中国期刊方阵“双效”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),波兰哥白尼索引,美国剑桥科学文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘,中国北大核心期刊(2000版)
  • 被引量:8029