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Sensitive and Selective Fluorescent and Colorimetric Sensor for Ag^+ Based on the Supramolecular Self-Assembly in Semi-Water
  • ISSN号:1001-604X
  • 期刊名称:《中国化学:英文版》
  • 时间:0
  • 分类:TQ126.35[化学工程—无机化工] TB383[一般工业技术—材料科学与工程]
  • 作者机构:Key Laboratory of Eco-Environment-Related Polymer Materials, Ministry of Education of China, Key Laboratory of Polymer Materials of Gansu Province, College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu 730070, China
  • 相关基金:Acknowledgement This work was supported by the National Natural Science Foundation of China (Nos. 21161018, 21262032, 21574104), the Program for Chang Jiang Scholars and hmovative Research Team in University of Ministry of Education of China (No. IRT1177).
中文摘要:

在用超级快方法的半水的离子的 ultratrace 层次的特定的识别仍然是为环境监视的挑战。此处,我们报导一荧光灯并且 colormetric 传感器(ZH ) 基于超分子自己组装,其结构被银离子的 ultratrace 的增加破坏。这个过程支持了可见颜色改变的肉眼或与一个宽 pH 范围一起熄灭的荧光紧张。系统的研究揭示了很高的选择(0.07

英文摘要:

Specific recognition of ultratrace levels of ions in semi-water using super-quicker methods is still a challenge for environmental monitoring. Herein we report a fluorescent and colormetric sensor (ZH) based on supramolecular self-assembly, whose structure was destroyed by the addition of ultratrace of silver ions. The process promoted either naked eye visible color changes or fluorescence intensity quenched in conjunction with a wide pH range. Systematic studies revealed very high selectivity (0.07 μmol/L) for silver ions, and other common cations, e.g., Hg^2+, Cu^2+, Cd^2+, Pb^2+ had nearly no influence on the sensing behavior. This sensor also served as a multiple use of component in sensing materials by addition of I^- into the mixture of ZH and Ag^+ (about 5 times). What's more, ZH containing filter paper emerged distinct color and fluorescence changes upon exposure to silver (Ag^+), which could be used as a portable method to undertake field testing for Ag^+.

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期刊信息
  • 《中国化学:英文版》
  • 主管单位:
  • 主办单位:中国化学会
  • 主编:
  • 地址:上海市枫林路354号中科院上海有机化学研究所
  • 邮编:200032
  • 邮箱:
  • 电话:021-54925243
  • 国际标准刊号:ISSN:1001-604X
  • 国内统一刊号:ISSN:31-1547/O6
  • 邮发代号:4-646
  • 获奖情况:
  • 中国期刊方阵“双高”期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国科学引文索引(扩展库),日本日本科学技术振兴机构数据库,英国英国皇家化学学会文摘
  • 被引量:175