采用传统固相反应法,研究了Li_2CO_3掺杂对0.94Mg_2SiO_4-0.06Ca_0.9Sr_0.1TiO_3微波介质陶瓷的烧结性能和介电性能的影响。结果表明,烧结助剂Li_2CO_3的引入未改变陶瓷的相组成。添加适量的Li_2CO_3可以促进烧结,烧结温度由1440℃降低到1355℃,而且介电性能也得到了优化,Q×f值有明显的提高;过量Li_2CO_3的引入,降低了材料的致密性,增加了陶瓷的介电损耗。在1355℃烧结,保温3h,添加0.50wt%Li_2CO_3的0.94Mg_2SiO_4-0.06Ca_0.9Sr_0.1TiO_3陶瓷获得最佳的介电性能:εr=7.96,Q×f=96409 GHz(f=14.571GHz),Tf=+4.62ppm/℃。
The effects of Li_2CO_3 on sintering and microwave dielectric properties of 0.94Mg_2SiO_4-0.06Ca_0.9Sr_0.1TiO_3 ceramics synthesized by a traditional solid-state reaction method were investigated. The results show that the addition of Li_2CO_3 did not change the phase of ceramics. Appropriate Li_2CO_3 addition could accelerate the sintering process, which could lower the sintering temperature from 1440 ℃ to 1355 ℃. Moreover, the addition of Li_2CO_3 improve the microwave dielectric properties and the Q ×f increases apparently. The decrease in density and deterioration of Q ×f were observed in the samples with excessive Li_2CO_3. The optimal microwave dielectric properties: εr = 7.96, Q ×f= 96409 GHz(f= 14. 571 GHz) Tf = + 4.62 ppm/℃ were obtained for 0.94Mg_2SiO_4-0.06Ca_0.9Sr_0.1TiO_3 doped with 0.50wt% Li_2CO_3 sintered at 1355 ℃ for 3 h.