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温度和紧实度对秸秆水解产酸的影响
  • ISSN号:1673-9108
  • 期刊名称:《环境工程学报》
  • 时间:0
  • 分类:X705[环境科学与工程—环境工程]
  • 作者机构:江苏省农业科学院农业资源与环境研究所,农业部农村可再生能源开发利用华东科学观测实验站,南京210014
  • 相关基金:国家水体污染控制与治理重大专项(2012ZX07101-004); 国家科技支撑计划项目(2014BAL02B04); 农业部公益性行业专项(201403019); 江苏省农业自主创新项目(CX(12)1002)
中文摘要:

为了解紧实度和温度对秸秆水解产酸过程的影响,以麦秸为原料,在不密封条件下,设置秸秆容重分别为0.03、0.05和0.08 t·m-3,水解温度为10、20和30℃,分析了实验过程中水解酸化液COD、SCOD、pH值、挥发性脂肪酸组成和含量的变化。结果表明:秸秆紧实度对秸秆有机物水解溶出速率影响明显,秸秆紧实度与秸秆有机物水解溶出速率成反比,与水解酸化液COD、SCOD和挥发性脂肪酸含量达到峰值的时间成正比,但在同等体积反应器内紧实度越大秸秆TS负荷越高,有利于提高水解酸化液COD、SCOD和VFAs浓度;秸秆紧实度对秸秆水解产酸产物的组成和含量影响明显,秸秆容重为0.03和0.05 t·m-3的处理水解产酸产物中乙酸占比达75%以上,丙酸、丁酸等含量较低,而秸秆容重为0.08 t·m-3的处理水解产酸产物中以丁酸和乙酸为主,为典型的丁酸型发酵,11 d后转变为丙酸型发酵;实验12 d后,不同紧实度处理水解酸化液中丙酸含量均逐渐增加;温度对秸秆有机物水解溶出的影响明显,水解酸化液COD、SCOD和pH值与温度成正比,温度高对秸秆有机物水解溶出有利,但同时也提高了可分解利用秸秆水解产酸产物的微生物活性,造成实验后期水解产酸产物大量损失。当温度为30℃时,水解产酸时间控制在5 d左右较合适,当温度为20℃时,水解产酸时间控制在2周左右较合适。

英文摘要:

The effects of temperature and compaction on hydrolysis and acidification of agricultural straw were investigated under laboratory conditions. In this study,wheat straw was used as the material. The bulk densities of wheat straw were 0. 03,0. 05,and 0. 08 t · m- 3,while the fermentation temperatures were 10,20,and30 ℃. The contents of chemical oxygen demand( COD),soluble COD( SCOD),and volatile solid acids( VFAs) and pH value were analyzed during the experiments. The results showed that a high bulk density of straw was unfavorable for the hydrolysis of wheat straw; a higher bulk density led to a lower hydrolysis rate of the organic matter of wheat straw and longer times required to reach the highest contents of COD,SCOD,and VFAs.However,a higher bulk density of straw means a larger mass of wheat straw in the same reactor volume,which leads to higher contents of COD,SCOD,and VFAs in the hydrolyzate. The composition and content of the hydrolyzate of wheat straw were also influenced by straw bulk density. In the treatments of wheat straw with bulk densities of 0. 03 and 0. 05 t·m- 3,acetic acid accounted for an absolute majority of the hydrolyzate,with low contents of propionic acid and butyric acid,while butyric acid and acetic acid were the main hydrolyzates in the treatment of wheat straw with a bulk density of 0. 08 t·m- 3. The treatment of wheat straw with a bulk density of0. 08 t · m- 3involved butyric-acid-type fermentation,which became propionic-acid-type fermentation after 11 days of reaction. The propionic acid content increased throughout the hydrolysis and acidification process. Temperature is one of the important factors in dissolution of wheat straw. COD and SCOD contents and pH value ofthe hydrolyzate were proportional to the temperature. A higher temperature was beneficial for dissolution of organic matter of straw. The activity of microbes that can decompose the hydrolyzate of wheat straw also increased,resulting in decreased hydrolyzate content after five days of reaction. Therefo

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期刊信息
  • 《环境工程学报》
  • 中国科技核心期刊
  • 主管单位:中国科学院
  • 主办单位:中国科学院生态环境研究中心
  • 主编:曲久辉
  • 地址:北京东黄城根北街16号
  • 邮编:100017
  • 邮箱:
  • 电话:010-62941074
  • 国际标准刊号:ISSN:1673-9108
  • 国内统一刊号:ISSN:11-5591/X
  • 邮发代号:82-448
  • 获奖情况:
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),英国英国皇家化学学会文摘
  • 被引量:20083