在过去的十几年中,M41S和SBA等介孔材料的出现极大地扩展了人们的视野.与传统的微孔沸石相比,介孔材料具有较大的孔径和较高的比表面积,因而更适于大分子催化和分离,以及纳米反应器等方面的应用,在一定程度上弥补了微孔分子筛的不足.但纯硅介孔材料的酸性比较弱,水热稳定性差,缺乏催化滑陛中心(其催化活性主要是通过修饰改性得到的)。
Highly ordered cubic Zr-doped mesoporous silica was directly prepared with Evaporation-Induced Self Assembly method(EISA) with triblock copolymers(Pluronic P123 ) as the structure-directing agents. The mesoporous material was characterized via small-angle powder X-ray diffraction (XRD) , transmission electron microscopy(TEM ), and nitrogen adsorption. The results show that the product has a face-centered cubic structure with space group of Fd3m. N2 sorption revealed that the Zr-doped mesoporous silica has not only ordered structures, but also high surface area(550 m^2/g) , large pore volume(0.66 cm^3/g) , as well as uniform pore size (4.0 nm).