研究了蓝藻中含量最多的色素——叶绿素在微囊藻毒素-LR(MC—LR)光催化降解中的作用,考察了波长和光强等对叶绿素催化的MC-LR光降解的影响.结果表明,叶绿素能导致MC-LR在日光照射下光降解,而且MC—LR的降解与其浓度呈正相关.在叶绿素浓度为0.1mg·ml^-1的条件下,日光照射30rainMC-LR的去除率即可达到95%以上,而叶绿素浓度为0.05mg·ml^-1和0.01mg·ml^-1时,照射30min后MC—LR的去除率分别为65%和56%.日光中紫外区(200-300nm)的光,在光催化降解MC—LR中起主要作用,与体系最大吸收光谱范围一致的240nm的光激发效果最好,光催化降解作用也最强.光照强度是影响MC—LR降解的重要因素,光强越大,MC—LR的降解率和降解速度越大.
The effect of chlorophyll, the most commonly pigment in cyanobacteria, on photocatalytic degradation of microcystin-LR(MC-LR) was studied. The influence of wavelength and intensity of light on MC-LR photocatalytic degradation was also investigated. The results showed that chlorophyll was a key factor on pbotocatalytic degradation of MC-LR, and the MC-LR degradation level was positively correlated with the concentration of chlorophyll. With the occurrence of 0. 1 mg · ml^-1 chlorophyll, over 95% of MC-LR was degraded after 30 minutes'sunlight irradiation, while with the aid of 0. 05 mg·ml^-1 and 0.01 mg· ml^-1 chlorophyll, only 65% and 56% of MC-LR was removed. The ultraviolet region (200--300 nm) of the sunlight played a dominant role in photocatalytic degradation of MC-LR, and 240 nm was the optimal for optical excitation and photocata- lytic degradation of MC-LR. The light intensity was also an important factor in MC-LR photocatalytic degrada- tion, as a higher light intensity resulted in a higher removal ratio and removal rate of MC-LR.