中文摘要：

这个工作证实开始和 anionic 聚合的繁殖机制的新看法以前求婚了，基于在自我的帮助下的苯乙烯和甲基苯乙烯的 anionic 体积聚合的调查设计了 microflow 设备并且由 GPC 并且在 situ 7Li NMR 描绘了。趋于形成聚集 hexameric 的结构并且弄平基于前者形成巨大的聚集的结构，被发现那 n-BuLi。开始者的这些聚集能直接开始 anionic 聚合并且形成 supramolecule 聚集。supramolecule 聚集不可避免地堵住了单体的散开到离子对并且导致了一个静止变换的平台。然后，集成者完全被分裂进相等的聚集二进制代码的种类，并且聚合在结束前很快再继续。Tetrahydrofuran (THF ) 充当了电子捐赠者，它能把电子云推到李阳离子并且做相当松开并且便于单体插入在里面的活跃种类的聚集的戒指。因此，小 THF 能极大地支持 anionic 聚合。然而， THF 的进一步的增加可能堵住在离子对和减少之间的隧道繁殖率。活跃种类的聚集的结构仅仅在 anionic 聚合期间取决于在聚合前被形成的开始者聚集，这也被发现。

英文摘要：

This work confirms the new view of the initiation and propagation mechanism of the anionic polymerization previously proposed, based on the investigation of anionic bulk-polymerization of styrene and α-methyl styrene with the help of a self designed microflow device and characterized by GPC and in situ ^7Li NMR. It was found that n-BuLl tended to form the hexameric-aggregated structure and even to form the huge aggregated structure based on the former. These aggregations of initiators could directly initiate the anionic polymerization and form the su-pramolecule aggregations. The supramolecule aggregations inevitably blocked the diffusion of the monomers to the ion-pairs and resulted in a stationary-conversion platform. Then the aggregators were dissociated completely into equal binary-aggregated species, and the polymerization continued again rapidly before the termination. Tetrahy-drofuran （THF） acted as the electron donator, which could push the electron cloud to Li cation and make the aggre- gated ring of the active species rather loosened and facilitated the monomer to insert in. Therefore, a little THF can greatly promote the anionic polymerization. However, further addition of THF might block the channel between the ion-pairs and decrease the propagation rate. It was also found that the aggregated structure of the active species during the anionic polymerization only depends on the initiator aggregations which were formed before the polym-erization.