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微乳液型油基钻井液冲洗液技术
  • ISSN号:1000-4092
  • 期刊名称:《油田化学》
  • 时间:0
  • 分类:TE256.7[石油与天然气工程—油气井工程]
  • 作者机构:[1]中国石油大学(华东)石油工程学院,山东青岛266580, [2]中国石油川庆钻探工程有限公司钻井液技术服务公司,四川成都610051
  • 相关基金:国家科技重大专项“复杂地层防塌钻井液与纳米微乳液冲洗技术研究”(项目编号2016ZX05020)和国家自然科学基金(项目编号51174226).
中文摘要:

为了高效清除井壁及套管壁上残留的油基钻井液、提高水泥环与环空界面胶结强度,根据表面活性剂盐水溶液与油接触后表面活性剂组装形成油水界面膜包裹油相而原位形成微乳液的原理,以琥珀酸二(2-乙基己酯)磺酸钠(AOT)、异构十三醇聚氧乙烯醚(AEO5-13)的复配体系为主表面活性剂,以柴油或白油为油相制备微乳液,通过考察微乳液增溶参数、界面张力等主要性能指标,确定了微乳液型冲洗液配方:KCl盐水(清洗柴油基钻井液时质量分数为7%,清洗白油基钻井液时质量分数为10%)+4%AOT+3%AEO5-13+6%正丁醇,并评价了该冲洗液的润湿反转能力、冲洗效率及与钻井液和水泥浆的相容性。研究结果表明,随盐度增加,微乳液相态经历Winsor Ⅰ型到Winsor Ⅲ型再到Winsor Ⅱ型的转变,Winsor Ⅲ型微乳液具有最佳的增溶参数和界面活性,形成Winsor Ⅲ型柴油微乳液及白油微乳液的最佳盐度分别为7%和10%。微乳液型冲洗液的润湿反转能力强、冲洗性能优越,7 min对油基钻井液冲洗效率达95%以上,且与钻井液及水泥浆的相容性好。

英文摘要:

Removing oil-based mud adhered to borehole and casing walls efficiently is crucial to develop an excellent cement bond of the interface and cementing quality. When the surfactant and salty solution contacts with the oil, the surfactant can form interracial film and wraps the oil, resulting in that the microemulsion is formed in situ. According to that, the microemulsions were prepared with sodium 2-ethylhexyl sulfosuccinate (AOT) and iso-tridecanol polyoxyethylene ether ( AE05 - 13 ) as surfactants, diesel or white oil as oil phase. Solubilization parameter and interface tension of the microemulsions were investigated and a formula of microemulsion flushing fluid was prepared: KCl salty water + 4% AOT+ 3% AEO5-13 + 6% n-butanol. The wettability alteration ability, flushing efficiency and the compatibility of microemulsion flushing fluid was evaluated. The experiment results showed that the microemulsion phase varied from Winsor Ⅰ to Winsor Ⅲ and then to Winsor Ⅱ with the increase of salt mass concentrations. The Winsor Ⅲ microemulsion possessed the optimum solubilization parameter and interracial activity, and the optimal salinity of Winsor Ⅲ dieesel microemulsion and white oil microemulsion was 7% and 10%, respectively. The density and theological property of microemulsion flushing fluid could be adjusted and its flushing ability was good. Performances evaluation showed that the wettability alteration ability of the flushing fluid was excellent, and the flushing efficiency for oil-based drilling fluid was higher than 95% in 7 min. The compatibility of microemulsion flushing fluid with oil-based drilling fluid and cementing slurry was excellent.

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期刊信息
  • 《油田化学》
  • 中国科技核心期刊
  • 主管单位:中国石油天然气集团公司
  • 主办单位:四川大学高分子研究所 高分子材料工程国家重点实验室
  • 主编:张熙
  • 地址:成都市四川大学西区
  • 邮编:610065
  • 邮箱:
  • 电话:028-85405414
  • 国际标准刊号:ISSN:1000-4092
  • 国内统一刊号:ISSN:51-1292/TE
  • 邮发代号:62-38
  • 获奖情况:
  • 中文核心期刊
  • 国内外数据库收录:
  • 美国化学文摘(网络版),荷兰文摘与引文数据库,美国石油文摘,日本日本科学技术振兴机构数据库,中国中国科技核心期刊,中国北大核心期刊(2004版),中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版),中国北大核心期刊(2000版)
  • 被引量:11698