由使用非平衡热力学的途径,为有身体气体和吸附的气体之间的温度差别的非平衡吸附的一个稳定的国家的存在的可能性被证实,稳定的国家是坚定的。身体气体和吸附的气体之间的化学潜在的差别被获得,为评估吸附熵和吸附的 isosteric 热的方程被导出。熵和在非平衡的吸附的 isosteric 热稳定的吸附的变化在平衡相对那些声明状态被计算,结果与用传统的平衡获得的那些相比是热力学的方法。比较建议吸附熵的变化和吸附的 isosteric 热获得了使用非平衡热力学的途径与不仅温度而且吸附的状态被联系,当那些获得了使用热力学的方法仅仅是的平衡时温度的功能。主要原因是现在的学习把吸附和煤气的温度变化当作一个综合过程并且考虑他们的相互作用,而热力学的途径分开的平衡吸附和二个独立人士处理并且忽视他们的相互作用的煤气的温度变化。
By using the non-equilibrium thermodynamic approach, the possibility of the existence of a steady state for non-equilibrium ad- sorption with a temperature difference between body gas and adsorbed gas was confirmed and the steady state was determined. The chemical potential difference between body gas and adsorbed gas was obtained and equations for evaluating the adsorption entropy and the isosteric heat of adsorption were derived. The changes of the adsorption entropy and the isosteric heat of adsorption at the non-equilibrium steady state relative to those at the equilibrium state were calculated and the results were compared with those obtained using the traditional equilibrium thermodynamic method. The comparison suggests that the changes of the adsorption entropy and the isosteric heat of adsorption obtained using the non-equilibrium thermodynamic approach are related with not only temperature but also adsorptive state, while those obtained using the equilibrium thermodynamic method are only a function of temperature. The main reason is that the present study treats the adsorption and gas temperature change as an integrated process and considers their interaction, whereas the equilibrium thermodynamic approach separates the adsorption and gas temperature change as two independent processes and neglects their interaction.