为寻求合理白度、节省资源、节能减排的漂白途径,研究了有机酸玉米秸秆皮生物炼制浆(OABCSRP)的短流程碱处理一二氧化氯一二氧化氯(ED1D2)无元素氯(ECF)漂白特性。结果表明:碱处理对OABCSRP具有良好的脱木质素选择性,是后续二氧化氯(D)漂白的重要基础,在浆浓10.0%(质量分数)、温度70℃、时间1.5h和用碱量4.0%的条件下碱处理,可获得率为95.4%、脱木质素率23.5%、黏度115mPa·s、白度44.2%(ISO)的纸浆;在碱处理过程中浆料中木质素和碳水化合物中的酯键发生了水解;ECF短流程ED1D2在4.0%NaOH及总ClO2用量3.6%条件下,经ED。D2漂白后,可获积累得率为88.0%、黏度124mPa·s、白度74.7%(ISO)的优良纸浆。
To obtain a bleaching process with a reasonable brightness, low consumption of fiber resource and energy, the bleaching properties of organic acid biorefinery corn stalk rind pulp (OABCSRP) by a short ECF bleaching process of ED1D2 were investigated in present study. The results indicates alkali extraction is high selective on delignification of OABCSRP, and the extraction is a foundation for next effective D1 D2 bleaching stages. A pulp with 95.4% yield, 23.5% delignification ratio, 115 mPa. s viscosity and 44.2% ISO brightness was obtained when pulp with 10.0% concentration was treated by 4.0% NaOH for 1.5 h at 70 ℃. Interesting findings revealed that the ester linkages between lignin and carbohydrate were hydrolyzed in the extraction process. The pulp with an accumulated yield 88.0%, 124 mPa· s and brightness 74.7% ISO respectively when 4. 0% NaOH and 3.6% ClO2 dosages were applied in ED, D2 bleaching. EDlD2 short bleaching process was suitable for OABCSRP bleaching to produce cultural papers.