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Fluorescence Detection for H_2PO_4~- based on Carbon Dots/Fe~(3+) Composite
  • ISSN号:1000-2413
  • 期刊名称:《武汉理工大学学报:材料科学英文版》
  • 分类:O613.71[理学—无机化学;理学—化学] TB33[一般工业技术—材料科学与工程]
  • 作者机构:[1]School of Civil Engineering and Architecture, Wuhan University of Technology, Wuhan 430070, China, [2]National Engineering Laboratory for Fiber Optic Sensing Technology, Wuhan University of Technology, Wuhan 430070, China
  • 相关基金:Funded by the National Natural Science Foundation of China(Nos.61575150 and 61377092); the Natural Science Foundation of Hubei Province(N0.2014CFB831)
中文摘要:

一篇小说荧光灯为 H 2 PO 4- 基于碳 dots/Fe 3+ 被设计并且制作合成。碳点被一个确定的一个壶综合热水的方法并且由传播电子显微镜, X 光检查衍射计,紫外力的吸收分光计和荧光分光光度计描绘了。碳 dots/Fe 3+ 合成被碳点和 FeCl 3, 的水的混合获得,它的荧光性质被荧光分光光度计描绘。碳点的荧光被水的 Fe 3+ 阳离子熄灭,导致碳 dots/Fe 3+ 的低荧光紧张合成。在另一方面, H 2 PO 4- 由化学反应减少了 Fe 3+ 的集中并且提高了碳 dots/Fe 3+ 的荧光合成。Stern-Volmer 方程被介绍描述在合成的碳 dots/Fe 3+ 和 H 2 PO 4-, 和好线性(R 2=0.997) 在 H 2 0.4-12 公里的 PO 4- 集中。

英文摘要:

A novel fluorescent probe for H_2PO_4~- was designed and fabricated based on the carbon dots/Fe~(3+) composite. The carbon dots were synthesized by an established one-pot hydrothermal method and characterized by transmission electron microscope, X-ray diffractometer, UV-Vis absorption spectrometer and fluorescence spectrophotometer. The carbon dots/Fe~(3+) composite was obtained by aqueous mixing of carbon dots and FeCl_3, and its fluorescence property was characterized by fluorescence spectrophotometer. The fluorescence of carbon dots was quenched by aqueous Fe~(3+) cations, resulting in the low fluorescence intensity of the carbon dots/Fe~(3+) composite. On the other hand, H_2PO_4~- reduced the concentration of Fe~(3+) by chemical reaction and enhanced the fluorescence of the carbon dots/Fe~(3+) composite. The Stern-Volmer equation was introduced to describe the relation between the relative fluorescence intensity of the carbon dots/Fe~(3+) composite and the concentration of H_2PO_4~-, and a fine linearity(R2=0.997) was found in the range of H_2PO_4~- concentration of 0.4-12 m M.

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期刊信息
  • 《武汉理工大学学报:材料科学英文版》
  • 中国科技核心期刊
  • 主管单位:
  • 主办单位:武汉理工大学
  • 主编:
  • 地址:武汉市洪山区珞狮路122号
  • 邮编:430070
  • 邮箱:jwutms@mail.whut.edu.cn
  • 电话:027-87384113 87651870
  • 国际标准刊号:ISSN:1000-2413
  • 国内统一刊号:ISSN:42-1680/TB
  • 邮发代号:38-78
  • 获奖情况:
  • 国内外数据库收录:
  • 被引量:149