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中文摘要：
以8-氨基喹啉,高氯酸锌和叠氮酸钠为原料,通过溶剂热反应合成了一种新型的单核配合物[Zn（8-aminoql）2（N3）]·Cl O4（1）,其结构经FT-IR,元素分析和X-射线单晶衍射表征。1（CCDC：1 028 430）属单斜晶系,P2/c空间群,晶胞参数a=8.445 2（7）,b=6.878 1（6）,c=16.437 3（13）,β=93.72（3）°,V=952.78（14）3,Z=2,Dc=1.726 g·cm-3,μ=1.474 mm-1,F（000）=504,R1=0.052 4,wR2=0.140 4[I〉2σ（I）]。中心Zn（II）为五配位构型,分别与五个N原子配位,其中4个N原子来自两个8-氨基喹啉配体,一个N原子来自N3-。1通过分子间弱的氢键（N-H┈O）和芳环间π…π堆积作用构成三维超分子结构。固体荧光性能测定结果表明：在355.0 nm波长激发下,1的最大发射波长位于516.4 nm。
英文摘要：
A new complex, [ Zn （8-aminoql） 2 （ N3 ） ] · C104 （ 1 ）, was synthesized by solvothermal reaction, using 8-aminoquinoline, Zn （ C104 ） 2 and NaN3 as raw material. The struxture was characterized by FT-IR, elemental analysis and single crystal X-ray diffraction. 1（ CCDC： 1 028 430） belongs to monoclinic, space group P2/c with a = 8. 445 2 （7） A, b = 6. 878 1 （6） A, c = 16.437 3 （13） A,,β =93.72（3）°, V =952.78（14）A3 , Z = 2, Dc = 1. 726 g · cm-3 , μ = 1. 474 mm-1 , F（000） = 504, R1 = 0.052 4, wR2 = 0. 140 4 [ I 〉 2σ-（I） ]. In 1, the Zn （II） has a distorted square pyramidal coordination geometry, and was coordinated by four nitrogen atoms from two 8-aminoql ligands, one nitrogen atom from one N3-. 1 presents a three-dimensional supramolecular structure via the N - H……O hydrogen bonds and π……π stacking interactions. The fluorescence property of 1 was investigated by FL. The results showed that λcm of 1 was 516.4 nm under 355.0 nm excitation.
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