在这份报纸,我们调查了 photogenerated 费用搬运人的再结合动力学在一 poly (3-hexylthiophene )(P3HT ):[6,6 ] 有在溶剂退火前后的 1:1 的施主领受人比率的 -phenyl-C61-butyric 酸甲基酉旨(PC61BM ) 混合系统处理。短暂光电流和 photovoltage 大小的技术被使用,并且费用搬运人是由在房间温度(298 K ) 的 7 ns 激光脉搏的 photogenerated。在短暂光电流测量,我们观察到在浸透的一些差别在 P3HT 提取了充电: 有不同力量效率的 PCBM 太阳能电池。另外,双分子的再结合系数被发现是 3.5 湩愠 ? 慨瑬湩吗?
In this paper, we investigated the recombination dynamics of photogenerated charge carriers in a poly(3-hexylthiophene) (P3HT):[6,6]-phenyl-Coj-butyric acid methyl ester (PC61BM) blend system with donor-acceptor ratio of 1 : 1 before and after sol- vent annealing treatment. The technique of transient photocurrent and photovoltage measurements were used, and charge carriers were photogenerated by a 7 ns laser pulse at room temperature (298 K). In transient photocurrent measurement, we observed some differences in the saturation extracted charge in P3HT:PCBM solar cells with different power efficiencies. In addition, the bimo- lecular recombination coefficient fl is found to be 3.5x10-13 cm3 s-1 for annealed devices, while 9.5x10-12 cm3 s-1 for as-cast de- vices. In the transient photovoltage measurement, we found that the photovoltage decay can be fitted by power-law equation at long time scale. The exponent parameter α is 2.6 for annealed devices, which can be described as trap-free bimolecular recombi- nation; α is 1.76 for as-cast device due to the trap-limited bimolecular recombination. These experimental results indicate that the nanomorphology of active layer indeed have influence on charge carriers dynamics in P3HT:PCBM blend systems.