采用等温溶解平衡法研究了五元体系Na^+,K^+,Mg^2+//Cl^-,NO3^--H2O在298.16K、氯化钠饱和时各盐的溶解度和饱和溶液的物化性质(密度,电导率)以及四元体系Na^+,Mg^2+//Cl^-,NO3^-- H2O的相平衡关系.研究表明:在298.16K,氯化钠饱和时该五元体系溶解度相图由六个结晶区、九条单变量溶解度曲线和四个零变量点构成,六个结晶区分别对应于NaNO3+NaCl,KNO3+NaCl,KCl+NaCl,Mg(NO3)2·6H2O+NaCl,MgCl2·6H2O+NaCl和复盐KCl·MgCl2·6H2O+NaCl:在298.16K时,该四元体系的相图由四个结晶区、五条单变量溶解度曲线和二个零变量点构成,四个结晶区分别对应于NaNO3,NaCl,Mg(NO3)2·6H2O,MgCl2·6H2O.
Solubilities of each salt in the system Na^+, K^+, Mg^2+//Cl^-, NO3 -H2O saturated with NaCl and the system Na^+, Mg^2+//Cl^-, NO3 ^--H2O were investigated by isothermal method at 298.16 K. The physico-chemical properties, such as densities and conductivities, of the corresponding solutions were determined too. The dry salt phase diagram of the system Na^+, K^+, Mg^2+//Cl^-, NO3 ^--H2O saturated with NaCl consists of six crystallization regions (NaNO3+NaCl, KNO3+NaCl, KCl+NaCl, Mg(NO3)2·6H2O+ NaCl, MgCl2·6H2O+NaCl and KCl·MgCl2·6H2O+NaCl), nine univariant curves and four invariant points. The dry salt phase diagram of the system Na^+, Mg^2+//Cl^-, NO3 -H2O consists of four crystallization regions (NaNO3, Mg(NO3)2·6H2O, MgCl2·6H2O and NaCl), five univariant curves and two invariant points.