ReCl(CO)5-catalyzed Reactions of Aromatic Compounds with 1,3,5-Trioxane or Aqueous Formaldehyde Affording Diarylmethanes
- ISSN号:1001-604X
- 期刊名称:《中国化学:英文版》
- 分类:O625.14[理学—有机化学;理学—化学]
- 作者机构:[1]Innovative Catalysis Program, Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
- 相关基金:Project supported by the National Natural Science Foundation of China (No. 20573061).
关键词:
芳族化合物, 脱水反应, 铼配合物, 催化剂, 1, 3, 5-三环氧乙烷, 福尔马林, 二芳基甲烷, aromatic, catalysis, dehydration, diarylmethane, trioxane
中文摘要:
ReCl (公司) 5 在空气下面与 1,3,5-trioxane 或水的甲醛(37 wt%) 催化芳香的混合物的脱水反应。与 1,3,5-trioxane 生捐赠电子的组的许多芳香的混合物的反应负担得起相应 diarylmethanes 在对好收益中等。
英文摘要:
ReCI(CO)5 catalyzed the dehydration reaction of aromatic compounds with 1,3,5-trioxane or aqueous formaldehyde (37 wt%) under air. The reactions of a variety of aromatic compounds beating electron-donating group(s) with 1,3,5-trioxane afforded the corresponding diarylmethanes in moderate to good yields.