Bell’s theorem states that quantum mechanics cannot be accounted for by any local theory. One of the examples is the existence of quantum non-locality is essentially violated by the local Bell’s inequality. Therefore, the violation of Bell’s inequality(BI) has been regarded as one of the robust evidences of quantum mechanics. Until now, BI has been tested by many experiments, but the maximal violation(i.e., Cirel’son limit) has never been achieved. By improving the design of entangled sources and optimizing the measurement settings, in this work we report the stronger violations of the Clauser–Horne–Shimony–Holt(CHSH)-type Bell’s inequality. The biggest value of Bell’s function in our experiment reaches √to a significant one: S = 2.772 ± 0.063, approaching to the so-called Cirel’son limit in which the Bell function value is S = 22.Further improvement is possible by optimizing the entangled-photon sources.