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碳纳米管改善水泥基材料性能的微观机理
  • ISSN号:1001-6864
  • 期刊名称:《低温建筑技术》
  • 时间:0
  • 分类:TQ127.2[化学工程—无机化工] O632.52[理学—高分子化学;理学—化学]
  • 作者机构:[1]School of Civil Engineering, Dalian University of Technology, Dalian 116024, China, [2]School-of Civil Engineering and Architecture, Xinxiang University, Xinxiang 453000, China
  • 相关基金:Supported by the the National Natural Science Foundation of China (No.51278086), PetroChina Innovation FundationfNo.2013D-5006-0606), the Program for New Century Excellent Talents in University by Ministry of Education of the People's Republic of China (No.NCET-12-0084), Liaoning BaiQianWan Talents of Science and Technology Program (No.2012921073), Henan Open and Cooperation Project of Science and Technology (No.142106000023) and Dalian Plan Projects of Science and Technology (No. 2013A 16GX 113 )
中文摘要:

硅藻土被用作原料由碱溶解方法与 3.1 的模量准备钠硅酸盐,结果的钠硅酸盐答案作为一位先锋被采用。甲基 methacrylate 单体通过答案沉浸在湿胶化被介绍,并且在在各种各样的退火下面在 70 点加热之上温度。ZnO 电影的特征被 XRD, FESEM,霍尔测量和光传播系列检验。结果证明 p 类型传导在李被观察做的 ZnO 电影在 500600 点退火了 ?? 疞鲝 ? 咑抑薵亘 ??? 錄 ?嶦 吗??

英文摘要:

Diatomite was used as raw material to prepare sodium silicate with a modulus of 3.1 by alkali dissolution method and the resulted sodium silicate solution was employed as a precursor. Methyl methaerylate monomers were introduced in wet gels through solution-immersion, and upon heating at 70 ℃, the mesoporous surfaces throughout the skeletal framework were coated with the polymer layer. PMMA modified silica aerogels were successfully synthesized via ambient pressure drying. The properties were investigated by FT- IR, NMR, TGA, nitrogen adsorption-desorption, FESEM and nano-indentation, etc. Results indicate that with the increasing of PMMA incorporated into silica aerogels, the bulk density and the BET surface area increase, the porosity decreases. Through the observation of FESEM, it is found that the interconnecting pores and the big pores add, the pore size distribution expands from 5-17 to 28-150 urn. By comparison, the PMMA modified silica aerogels achieve a 52-fold increase in hardness and a 10-fold increase in modulus.

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期刊信息
  • 《低温建筑技术》
  • 主管单位:黑龙江省城乡和住房建设厅
  • 主办单位:黑龙江寒地院
  • 主编:张锦屏
  • 地址:哈尔滨市南岗区清滨路60号
  • 邮编:150080
  • 邮箱:Lowtem@163.com
  • 电话:0451-86335022 86334097
  • 国际标准刊号:ISSN:1001-6864
  • 国内统一刊号:ISSN:23-1170/TU
  • 邮发代号:14-122
  • 获奖情况:
  • 中国期刊全文数据库全文收录期刊《CAJ-CD规范》...,中国科技论文统计源期刊(中国科技核心期刊),中国学术期刊综合评价数据库统计源期刊
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  • 被引量:8377