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农业源头沟渠沉积物氮磷吸附特性研究
  • ISSN号:1672-2043
  • 期刊名称:《农业环境科学学报》
  • 时间:0
  • 分类:X502[环境科学与工程—环境工程]
  • 作者机构:[1]清华大学环境科学与工程系,北京100084, [2]中国环境科学研究院,北京100012, [3]北京化工大学环境工程系,北京100029
  • 相关基金:基金项目:国家重点基础研究发展规划(973)项目(2002CB410800-07),(2005CB724203),(2002CB412302)
中文摘要:

通过吸附实验,研究了杭嘉湖流域某源头沟渠中沉积物对氨氮和磷酸盐的吸附动力学及吸附等温线特征,以揭示氮、磷迁移转化机制。结果表明,沉积物对氨氮和磷酸盐的吸附是一个复合动力学过程,包括快速吸附和慢速吸附2个阶段,主要吸附过程发生在0~5h之内,吸速率在0~1h较大,氨氮最大吸附速率为160mg·kg^-1·h^-1,磷酸盐最大吸附速率为300mg·kg^-1·h^-1。实验浓度范围内(氨氮0-50mg·L^-1,磷酸盐0-20mg·L^-1)沟渠沉积物对氨氮和磷酸盐的吸附等温线均呈良好线性变化。沉积物中固定态氨氮含量为9.81mg·kg^-1,沉积物对磷的吸附-解吸平衡质量浓度为0.046mg·L^-1,与同流域内湖泊河流相比均较低。说明氮、磷在农田沟渠中的迁移转化较快,与河流湖泊相比,氮、磷并未大量累积在沉积物中。

英文摘要:

Agriculture non-point pollution is attracting increasing interests. Interests are focused on the excess nutrient such as nitrogen (N) and phosphorus (P)which can lead to eutrophication. As the main connecting part between fields and lake or river, agricultural ditch system plays an important role in the retention of N and P. During the transportation and transformation in ditch system, N and P can be held up by some ways such as adsorption, nitrification, denitrification and emergent uptake. Adsorption is one of the important retention factors. Static adsorption experiments were performed to investigate the adsorption kinetic and isotherm characteristics of ammonia nitrogen and phosphate on ditch sediments. The results help to explain the mechanism of transportation and transformation of N and P as to control the loss N and P. The results showed that the adsorption included two phases:fast and slow adsorption. The adsorption on sediment mainly occurred within 0-5 h and the maximum adsorption rates of ammonia nitrogen and phosphate on ditch sediment were 160 mg·kg^-1·h^-1 and 300 mg·kg^-1·h^-1 respectively. The adsorption isotherms of ammonia nitrogen and phosphate fitted well with linear relation. The content of immobile ammonium in the sediment was 9.81 mg·kg^-1. The adsorption-resorption equilibrium concentration of phosphate was 0.046 mg·L^-1. According to above results, N and P did not accumulate much in ditches as that in other waters.

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期刊信息
  • 《农业环境科学学报》
  • 北大核心期刊(2011版)
  • 主管单位:中华人民共和国农业部
  • 主办单位:农业部环境保护科研监测所 中国农业生态环境保护协会
  • 主编:李文华
  • 地址:天津市南开区复康路31号
  • 邮编:300191
  • 邮箱:caep@vip.163.com
  • 电话:022-23674336 23006209
  • 国际标准刊号:ISSN:1672-2043
  • 国内统一刊号:ISSN:12-1347/S
  • 邮发代号:6-64
  • 获奖情况:
  • 全国中文核心期刊,列于被引频比最高的中国科技期刊500名之内
  • 国内外数据库收录:
  • 俄罗斯文摘杂志,美国化学文摘(网络版),英国农业与生物科学研究中心文摘,美国剑桥科学文摘,中国中国科技核心期刊,中国北大核心期刊(2008版),中国北大核心期刊(2011版),中国北大核心期刊(2014版)
  • 被引量:34877