中文摘要：

多介质流体动力学过程的数值模拟往往涉及混合物状态方程的计算．做图法和Newton法是混合物状态方程计算常采用的方法，前者虽直观精度却差，后者计算效率高却只具有局部收敛性，当解与其初始猜测值相差较远时Newton法不一定能够获得收敛解．为此，本文给出一种具有大范围收敛性的嵌入算法（imbeddingmethod）求解混合物状态方程，其基本思想是通过引入嵌入参数，将待解的混合物状态方程和易解的混合物状态方程线性组合，构成嵌入方程组，当嵌入参数从0连续地变化到1时，嵌入方程组的解由易解的混合物状态方程的解连续地变化为待解的混合物状态方程的解．嵌入方程组可由Newton法迭代求解，也可转化为以嵌入参数为自变量的常微分方程组，从而易于由成熟的计算方法如梯形法等进行求解．进一步利用热力学基本关系，Maxwell形式的微分方程描述了压力和温度随嵌入参数的演化速率与应变速率和组分质量分数演化速率的关系．对铅锡混合物热力学量的计算表明了本文算法的有效性．

英文摘要：

The problem of calculating the equation of state （EOS） of a material mixture often comes from fluid-dynamical system containing multiple materials. Generally, the EOS of a material mixture is a system of nonlinear equations which are usually solved by the tabular method and the Newton iterative method. However, the former has poor accuracy, and the later has a finite radius of convergence and hence will converge only if the initial guess is sufficiently close to the final solution. So, a procedure different from the above two method is presented for calculating the EOS of a material mixture whose constituents are in pressure equilibrium and temperature equilibrium. An imbedding method is used to determine the constituent partial thermodynamic variables subjected to the constraints that the total volume and energy of mixture and the constituent mass fractions are specified. The imbedding method has a large radius of convergence, introducing a parameter defined in the interval [0, 1] and a system of imbedding equations which is linearly composed of the to-be-solved EOS of a material mixture and the easy-to-solve EOS of a material mixture. While the parameter changes continuously from 0 to 1, the imbedding method continuously changes the solution of the to-be-solved EOS which the easy-to-solve EOS of a material mixture is continuously converted into. The system of imbedding equations can be changed into a system of ordinary differential form by taking the parameter as independent variable, easily solved by a matured computational method such as trapezoidal rule. By using thermodynamic formulae, two equations in the generalized Maxwellian form are obtained, relating respectively the pressure rate and temperature rate to the strain rate and the constituent mass fraction rate. Finally, the computational method is verified by calculating the EOS of various mass fractions of lead and tin mixture.