以石蜡基减三线石油磺酸钠与Ca Cl2水溶液发生复分解反应生成中性磺酸钙,在促进剂的作用下进行钙化反应后制得石蜡基石油磺酸钙。对原料的处理分析、复分解反应收率及复分解反应前后金属离子的考察分析表明,复分解反应后生成的中性磺酸钙收率在95%以上,钠离子含量由20 000×10-6降低至约8 000×10-6,钙离子由12.8×10-6提高至约8 000×10-6。当25%Ca Cl2溶液、反应温度控制在60℃、反应时间3 h,复分解反应效果最佳。
Neutral calcium sulfonate was produced from metathesis of vacuum cut 3's paraffin base petroleum sodiumsulfonate and Ca Cl2,which had calcification reaction under the effect of promoter to prepare paraffin base petroleum calcium sulfonate. According to the investigation and analysis result of the processed raw materials,the yield and the metalion content,the yield of neutral calcium sulfonate after metathesis was above 95%,sodium ion content was decreased from20 000×10-6to 8 000×10-6,calcium ion content was increased from 12.8×10-6to 8 000×10-6. During the metathesis process,the reaction temperature of 25% Ca Cl2 solution was 60 ℃ with the 3 h reaction time,and the best reaction effect was found.